Microstructure and contact resistivity of (Bi, Sb)2Te3/Sb interface

被引:8
|
作者
Li, Fei [1 ,2 ]
Huang, Xiangyang [1 ]
Jiang, Wan [3 ]
Chen, Lidong [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, 1295 Dingxi Rd, Shanghai 200050, Peoples R China
[2] Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Donghua Univ, Coll Mat Sci & Engn, Shanghai 200051, Peoples R China
基金
国家高技术研究发展计划(863计划); 中国国家自然科学基金;
关键词
Thermoelectric; Interlayer; Antimony; Contact resistivity; ANTIMONY TELLURIDE; ALLOYS; POWER;
D O I
10.1063/1.4731595
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Thermoelectric joint composed of Bi0.5Sb1.5Te3 (BiSbTe) material and antimony (Sb) metallic interlayer was fabricated by Spark Plasma Sintering. The reliability of the joints was investigated by interfacial microstructure evolution using electron probe micro-analysis for the samples with different accelerated isothermal aging time. After aging for 30 days in vacuum, the thickness of diffusion layer is about 50 mu m. Sb2Te3 was identified to be the major interfacial compound. The contact resistivity, depending on the thickness of interfacial compound, is 3 x 10(-6) ohm cm(2) before aging and increases to 8.5 x 10(-6) ohm cm(2) after aging for 30 days. The contact resistivity of thermoelectric material/Sb interface is very small as compared to that of solder alloys as interlayer. This study provides a new interlayer-Sb to be used in the bismuth telluride based thermoelectric module.
引用
收藏
页码:458 / 462
页数:5
相关论文
共 50 条
  • [31] (BI0.5SB0.5)2TE3 CRYSTALS DOPED WITH INDIUM ATOMS
    LOSTAK, P
    NAVRATIL, J
    SRAMKOVA, J
    HORAK, J
    PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 1993, 135 (02): : 519 - 526
  • [32] DEFORMATION AND RECRYSTALLIZATION STRUCTURES AND ELECTRICAL-PROPERTIES OF EXTRUDED (SB, BI)2TE3
    GORELIK, SS
    DUBROVINA, AN
    KOSHELEVA, MN
    LEKSINA, RK
    INORGANIC MATERIALS, 1978, 14 (06) : 822 - 824
  • [33] Reaction evolution and alternating layer formation in Sn/(Bi0.25Sb0.75)2Te3 and Sn/Sb2Te3 couples
    Chen, Sinn-wen
    Wu, Hsin-jay
    Wu, Chih-yu
    Chang, Chun-fei
    Chen, Chung-yi
    JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 553 : 106 - 112
  • [34] Ferromagnetic Layers in a Topological Insulator (Bi,Sb)2Te3 Crystal Doped with Mn
    Frolov, Alexander S.
    Usachov, Dmitry Yu.
    V. Fedorov, Alexander
    Vilkov, Oleg Yu.
    Golyashov, Vladimir
    Tereshchenko, Oleg E.
    Bogomyakov, Artem S.
    Kokh, Konstantin
    Muntwiler, Matthias
    Amati, Matteo
    Gregoratti, Luca
    Sirotina, Anna P.
    Abakumov, Artem M.
    Sanchez-Barriga, Jaime
    Yashina, Lada, V
    ACS NANO, 2022, 16 (12) : 20831 - 20841
  • [35] Zero-field quantized anomalous Hall resistance of (Bi,Sb)2Te3
    Goetz, Martin
    Fijalkowski, Kajetan M.
    Pesel, Eckart
    Hartl, Matthias
    Schreyeck, Steffen
    Winnerlein, Martin
    Grauer, Stefan
    Scherer, Hansjoerg
    Brunner, Karl
    Gould, Charles
    Ahlers, Franz J.
    Molenkamp, Laurens W.
    2018 CONFERENCE ON PRECISION ELECTROMAGNETIC MEASUREMENTS (CPEM 2018), 2018,
  • [36] Size dependence of electrical resistivity and energy bandgap of semiconducting (Bi0.4Sb0.6)2Te3 thin films
    Das, VD
    Ganesan, PG
    PHYSICS OF SEMICONDUCTOR DEVICES, VOLS 1 AND 2, 1998, 3316 : 1157 - 1160
  • [37] Scanning thermoelectric microscopy of local thermoelectric behaviors in (Bi,Sb)2Te3 films
    Zhao, Kunyu
    Zeng, Huarong
    Xu, Kunqi
    Yu, Huizhu
    Li, Guorong
    Song, Junqiang
    Shi, Xun
    Chen, Lidong
    PHYSICA B-CONDENSED MATTER, 2015, 457 : 156 - 159
  • [38] Thermal Conductivity for p-(Bi, Sb)2Te3 Films of Topological Insulators
    Lukyanova, Lidia N.
    Boikov, Yuri A.
    Usov, Oleg A.
    Danilov, Viacheslav A.
    Makarenko, Igor V.
    Petrov, Vasilii N.
    MAGNETOCHEMISTRY, 2023, 9 (06)
  • [39] Microstructural characterization of Cr-doped (Bi, Sb)2Te3 thin films
    Tarakina, N. V.
    Schreyeck, S.
    Duchamp, M.
    Karczewski, G.
    Gould, C.
    Brunner, K.
    Dunin-Borkowski, R. E.
    Molenkamp, L. W.
    CRYSTENGCOMM, 2017, 19 (26): : 3633 - 3639
  • [40] Robust (Bi,Sb)2Te3 Thermoelectrics Due to Engineered Ion Confinement and Microstructure for Advancing Thermoelectric Power Generators
    Li, Ruyuan
    Wu, Gang
    Zhang, Qiang
    Pan, Qiaoyan
    Wang, Min
    Pang, Kaikai
    Miao, Liya
    Tan, Xiaojian
    Sun, Peng
    Hu, Haoyang
    Wu, Jiehua
    Liu, Guo-Qiang
    Jiang, Jun
    ADVANCED FUNCTIONAL MATERIALS, 2025,