Crystal structures of a calix[4]arene controlled by two affixed pyrene units

被引:6
|
作者
Gruber, Tobias [1 ]
Seichter, Wilhelm [1 ]
Weber, Edwin [1 ]
机构
[1] Tech Univ Bergakad Freiberg, Inst Organ Chem, D-09596 Freiberg, Germany
关键词
calixarenes; crystalline inclusion compound; X-ray crystal structures; supramolecular interactions; pyrene stacking;
D O I
10.1080/10610270701854945
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis and crystal structures of a calix[4]arene (1) with two affixed pyrene units and its corresponding inclusion compound with chloroform (1a) are reported. In both cases, stacking structures resulting from the influencing control of the pyrene units are observed. The occurrence of infinite or dimeric stack motifs of the pyrene units is dependent on the absence or presence of the included guest solvent. [image omitted].
引用
收藏
页码:753 / 760
页数:8
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