Recent Progress on Establishing Structure-Activity Relationship of Catalysts for Selective Catalytic Reduction (SCR) of NOx with NH3

被引:20
|
作者
Huang, Xiaosheng [1 ,2 ]
Zhang, Guodong [1 ]
Lu, Gongxuan [1 ]
Tang, Zhicheng [1 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Natl Engn Res Ctr Fine Petrochem Intermediates, Lanzhou 730000, Gansu, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China
基金
中国科学院西部之光基金; 中国国家自然科学基金;
关键词
SCR catalyst; NOx control; Structure-activity relationship; Reaction mechanism; Research progress; MIXED-OXIDE CATALYST; LOW-TEMPERATURE SCR; NITRIC-OXIDE; NH3-SCR REACTION; NITROGEN-OXIDES; CHEMICAL DEACTIVATION; COMMERCIAL CATALYSTS; MNOX-CEO2; MECHANISM; MESOPOROUS SILICA; LUBRICATION OILS;
D O I
10.1007/s10563-017-9237-y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Catalytic elimination is an important technique to reduce the emission of atmospheric molecular contaminants (such as NOx) efficiently. Selective catalytic reduction (SCR) is one of the most important nitrogen oxide (NOx) control technologies in the world, and catalyst plays a greatly important role in SCR process. In this field, the novel catalysts and preparation methods have attracted more and more attention in recent years due to their excellent catalytic performance. It is well accepted that catalytic performance is significantly dependent on the supports, active sites, and interaction of support and active component of the catalysts. In this paper, we present a brief review on the preparation methods of different kinds of SCR catalysts in recent years and propose some perspectives for further development. Based on the report of published literatures, the structure-activity relationship between support and active sites is deeply analyzed. Meanwhile, we review the possible catalytic mechanism, and further clarify the nature of the catalytic reactions.
引用
收藏
页码:1 / 19
页数:19
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