Process Synthesis: Selective Recovery of Lithium from Lithium-Ion Battery Cathode Materials

被引：33

作者：

Li, Quan ^{[1
]}

Fung, Ka Yip ^{[1
]}

Xu, Lingda ^{[1
]}

Wibowo, Christianto ^{[2
]}

Ng, Ka Ming ^{[1
]}

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem & Biol Engn, Clear Water Bay, Hong Kong, Peoples R China

[2] ClearWaterBay Technol Inc, 671 Brea Canyon Rd,Suite 5, Walnut, CA 91789 USA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2019年 / 58卷 / 08期

关键词：

VALUABLE METALS; THERMAL-DECOMPOSITION; OXALATE DIHYDRATE; HYDROMETALLURGICAL PROCESS; DESIGN ALTERNATIVES; ACTIVE MATERIAL; PHASE-DIAGRAMS; TARTARIC ACID; CRYSTALLIZATION; COBALT;

D O I：

10.1021/acs.iecr.8b04899

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A selective dissolution process to recover lithium from cathode materials by oxalic acid was investigated. The chemical reaction responsible for dissolution was identified, and the effects of operating parameters including temperature, acid concentration, as well as solid-to-liquid feed ratio on lithium recovery were studied using LiNi0.5Mn0.3Co0.2O2 (NMC-532) as the base case cathode materials, leading to a lithium recovery of 96.3% from cathode materials. However, 2.16% of manganese was also dissolved with lithium. An integrated process based on chemical and antisolvent precipitation was synthesized to separate and recover manganese and lithium with high recovery and high purity from the liquid after dissolution. This process was also shown to work on other cathode materials including LiNixMnyCo1-x-yO2 of various metal ratios, LiMn2O4 and LiCo0.95Mn0.05O2.

引用

页码：3118 / 3130

页数：13

共 50 条

[31] Integrated Combinatorial Synthesis, Characterization, and Test Platform for Lithium-Ion Battery Cathode Materials
Xiao, Yunhao
Zheng, Panni
Yang, Tairan
Chakravarty, Sriya Karambor
Rodriguez-Lopez, Joaquin
Urban, Alexander
Li, Zheng
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2023, 170 (05)
[32] Lithium transport through lithium-ion battery cathode coatings
Xu, Shenzhen
Jacobs, Ryan M.
Nguyen, Ha M.
Hao, Shiqiang
Mahanthappa, Mahesh
Wolverton, Chris
Morgan, Dane
[J]. JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (33) : 17248 - 17272
[33] Resource Recovery of Spent Lithium-Ion Battery Cathode Materials by a Supercritical Carbon Dioxide System
Fu, Yuanpeng
Dong, Xianshu
Ebin, Burcak
[J]. MOLECULES, 2024, 29 (07):
[34] Synthesis of Diverse LiNixMnyCozO2 Cathode Materials from Lithium Ion Battery Recovery Stream
Sa Q.
Gratz E.
Heelan J.A.
Ma S.
Apelian D.
Wang Y.
[J]. J. Sust. Metal., 3 (248-256): : 248 - 256
[35] Recovery of cathode materials and Al from spent lithium-ion batteries by cleaning
He, Li-Po
Sun, Shu-Ying
Song, Xing-Fu
Yu, Jian-Guo
[J]. WASTE MANAGEMENT, 2015, 46 : 523 - 528
[36] Recovery of cathode materials from spent lithium-ion batteries using eutectic system of lithium compounds
Ji, Yi
Jafvert, Chad T.
Zhao, Fu
[J]. RESOURCES CONSERVATION AND RECYCLING, 2021, 170
[37] Recovery of cathode materials from spent lithium-ion batteries using eutectic system of lithium compounds
Ji, Yi
Jafvert, Chad T.
Zhao, Fu
[J]. Resources, Conservation and Recycling, 2021, 170
[38] Solvometallurgical recovery of cobalt from lithium-ion battery cathode materials using deep-eutectic solvents
Peeters, Nand
Binnemans, Koen
Riano, Sofia
[J]. GREEN CHEMISTRY, 2020, 22 (13) : 4210 - 4221
[39] A novel recovery process of metal values from the cathode active materials of the lithium-ion secondary batteries
Wang, Rong-Chi
Lin, Yu-Chuan
Wu, She-Huang
[J]. HYDROMETALLURGY, 2009, 99 (3-4) : 194 - 201
[40] Study on Roasting for Selective Lithium Leaching of Cathode Active Materials from Spent Lithium-Ion Batteries
Jung, Yeonjae
Yoo, Bongyoung
Park, Sungcheol
Kim, Yonghwan
Son, Seongho
[J]. METALS, 2021, 11 (09)

← 1 2 3 4 5 →