The sharpness of melting maxima

被引：3
|
作者：
Selleby, M [1 ]
Hillert, M [1 ]
机构：
[1] KTH Royal Inst Technol, Dept Mat Sci & Engn, SE-10044 Stockholm, Sweden
来源：
JOURNAL OF PHASE EQUILIBRIA | 1999年 / 20卷 / 03期
关键词：
D O I：
10.1361/105497199770335802
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The shape of melting maxima for strictly stoichiometric phases Is examined by computer calculations. For a simplified case, it is found that such maxima look sharp, in apparent violation of Konovalov's rule, if the Gibbs energy of formation of the phase is -20T(m) J/mole of atoms or lower (more negative).
引用
收藏
页码：288 / 294
页数：7
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