The sharpness of melting maxima

被引：3

作者：

Selleby, M ^{[1
]}

Hillert, M ^{[1
]}

机构：

[1] KTH Royal Inst Technol, Dept Mat Sci & Engn, SE-10044 Stockholm, Sweden

来源：

JOURNAL OF PHASE EQUILIBRIA | 1999年 / 20卷 / 03期

关键词：

D O I：

10.1361/105497199770335802

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The shape of melting maxima for strictly stoichiometric phases Is examined by computer calculations. For a simplified case, it is found that such maxima look sharp, in apparent violation of Konovalov's rule, if the Gibbs energy of formation of the phase is -20T(m) J/mole of atoms or lower (more negative).

引用

页码：288 / 294

页数：7

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