[ReOCl3(PPh3)2] as a substrate for the synthesis of the rhenium(I) carbonyl complexes [Re(CO)2(OAc)(PPh3)2] and [ReCl(CO)3(PPh3)2]

被引：2

作者：

Krawczyk, Monika K. ^{[1
]}

Krawczyk, Marta S. ^{[1
]}

Siczek, Milosz ^{[1
]}

Lis, Tadeusz ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2013年 / 733卷

关键词：

Rhenium carbonyl complex; Acetic anhydride; Decarbonylation; PENTACARBONYL; PERCHLORATE; LIGANDS;

D O I：

10.1016/j.jorganchem.2013.03.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New preparative methods have been developed for the synthesis of the rhenium(I) carbonyl complexes [Re(CO)(2)(OAc)(PPh3)(2)] (1) and [ReCl(CO)(3)(PPh3)(2)] (2). Acetic anhydride was decarbonylated during the course of its reaction with [ReOCl3(PPh3)(2)], resulting in the formation of the rhenium(I) carbonyl complex [Re(CO)(2)(OAc)(PPh3)(2)] (1), which was subsequently converted almost quantitatively to [ReCl(CO)(3)(PPh3)(2)] (2) via the decarbonylation of its acetate group under acidic conditions. (C) 2013 Elsevier B. V. All rights reserved.

引用

页码：60 / 62

页数：3

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