Photoactivation of metal-halogen bonds in a Ni(II) NHC complex

被引：18

作者：

Lee, Chang Hoon ^{[1
]}

Lutterman, Daniel A. ^{[1
]}

Nocera, Daniel G. ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 07期

关键词：

SOLAR-ENERGY; PHOTOREDUCTIVE ELIMINATION; HYDROGEN-PRODUCTION; CHEMISTRY; OXYGEN; LIGAND; PHOTOELIMINATION; GENERATION; WORLDS;

D O I：

10.1039/c2dt32885b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Photolysis of [Ni-II(mu-Cl)Cl(IPr)](2) (IPr = 1,3-bis(2,6-diisopropylphenyl) imidazol-2-ylidene) activates the Ni-Cl bonds to furnish [Ni-I(mu-Cl)(IPr)](2). Consistent with this photochemistry, a TD-DFT calculation for square planar Ni(II) centre reveals that light excitation leads to the population of orbitals with sigma*(Ni-Cl) character.

引用

下载

页码：2355 / 2357

页数：3

共 50 条

[41] Type II halogen...halogen contacts are halogen bonds
Metrangolo, Pierangelo
Resnati, Giuseppe
IUCRJ, 2014, 1 : 5 - 7
[42] Investigation of the metal-halogen exchange reaction of a bromobenzo[b]thiophene.
Kolakowski, GR
Kasar, RA
Kim, M
Bjornson, KL
Jacobson, I
Farouz, FS
Thorsett, ED
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U347 - U348
[43] Metal-Halogen Exchange-Initiated Cyclization Reactions of Dienes and Enynes
Cooke, M. P.
Huang, J.-J.
Synlett,
[44] APPLICATION OF THE METAL-HALOGEN EXCHANGE-REACTION TO CYCLIC AND POLYMERIC ORGANOPHOSPHAZENES
FULLER, TJ
EVANS, TL
ALLCOCK, HR
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1979, (SEP): : 262 - 262
[45] Preparation of substituted alkoxypyridines via directed metalation and metal-halogen exchange
Bori, Ibrahim D.
Comins, Daniel L.
ARKIVOC, 2021, : 57 - 72
[46] THERMODYNAMIC DATA ON BOND-ENERGIES OF METAL-HALOGEN, METAL-OXYGEN, METAL-METAL
DROBOT, DV
PISAREV, EA
ZHURNAL NEORGANICHESKOI KHIMII, 1981, 26 (01): : 3 - 16
[47] Metal-halogen exchange-initiated cyclization reactions of dienes and enynes
Cooke, MP
Huang, JJ
SYNLETT, 1997, (05) : 535 - &
[48] REGIOCHEMISTRY OF THE METAL-HALOGEN EXCHANGE INDUCED CYCLIZATION OF OMEGA-IODOEPOXIDES
COOKE, MP
HOUPIS, IN
TETRAHEDRON LETTERS, 1985, 26 (31) : 3643 - 3646
[49] Unique behavior of lattice modulation phase induced by ligand motion of a mixed-valence metal-halogen complex
Araoka, Fumito
Kobayashi, Takayoshi
ULTRAFAST PHENOMENA XV, 2007, 88 : 609 - +
[50] METAL-HALOGEN BONDING STUDIES WITH GROUP-IVA TRIALKYLMETAL HALIDES
FRIEDRICH, EC
ABMA, CB
VARTANIAN, PF
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 187 (02) : 203 - 211

← 1 2 3 4 5 →