Catalytic conversion of fructose and sucrose to 5-hydroxymethylfurfural using simple ionic liquid/DMF binary reaction media

被引：18

作者：

Shi, Jincai ^{[1
]}

Yang, Yan ^{[1
]}

Wang, Ningning ^{[1
]}

Song, Zhanxin ^{[1
]}

Gao, Haiyan ^{[1
]}

Xia, Yongmei ^{[1
,2
]}

Li, Wei ^{[1
]}

Wang, Haijun ^{[1
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Peoples R China

[2] Jiangnan Univ, State Key Lab Food Sci & Technol, Wuxi 214122, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2013年 / 42卷

关键词：

5-Hydroxymethylfurfural; Fructose; Ionic liquid; N; N-Dimethylformamide; System; ROOM-TEMPERATURE; SELECTIVE DEHYDRATION; LEVULINIC ACID; EFFICIENT; CELLULOSE; GLUCOSE; DMSO;

D O I：

10.1016/j.catcom.2013.08.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The production of 5-hydroxymethylfurfural (HMF) from carbohydrates has been reported intensively in recent years. HMF is believed to be a versatile platform chemical and the focus of synthesizing it has especially been on the development of efficient catalysts, such as Lewis and Bronsted Acids. On the contrary, herein, we report a novel catalytic system that consists of 1-allyl-3-methylimidazolium chloride ([AMIM]Cl) and N,N-Dimethylformamide (DMF) without any additional metal salts or acids, which leads to reasonable HMF yields (84.9%) and selectivities. In addition, the degradation mechanism of fructose catalyzed by [AMIM]Cl is also proposed in this communication. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：89 / 92

页数：4

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