Catalytic conversion of fructose and sucrose to 5-hydroxymethylfurfural using simple ionic liquid/DMF binary reaction media

被引：18
|
作者：
Shi, Jincai [1 ]
Yang, Yan [1 ]
Wang, Ningning [1 ]
Song, Zhanxin [1 ]
Gao, Haiyan [1 ]
Xia, Yongmei [1 ,2 ]
Li, Wei [1 ]
Wang, Haijun [1 ]
机构：
[1] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Peoples R China
[2] Jiangnan Univ, State Key Lab Food Sci & Technol, Wuxi 214122, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2013年 / 42卷
关键词：
5-Hydroxymethylfurfural; Fructose; Ionic liquid; N; N-Dimethylformamide; System; ROOM-TEMPERATURE; SELECTIVE DEHYDRATION; LEVULINIC ACID; EFFICIENT; CELLULOSE; GLUCOSE; DMSO;
D O I：
10.1016/j.catcom.2013.08.009
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The production of 5-hydroxymethylfurfural (HMF) from carbohydrates has been reported intensively in recent years. HMF is believed to be a versatile platform chemical and the focus of synthesizing it has especially been on the development of efficient catalysts, such as Lewis and Bronsted Acids. On the contrary, herein, we report a novel catalytic system that consists of 1-allyl-3-methylimidazolium chloride ([AMIM]Cl) and N,N-Dimethylformamide (DMF) without any additional metal salts or acids, which leads to reasonable HMF yields (84.9%) and selectivities. In addition, the degradation mechanism of fructose catalyzed by [AMIM]Cl is also proposed in this communication. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：89 / 92
页数：4
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