Thienylmanganese halides for the preparation of regioregular poly(3-hexylthiophene)

被引：6

作者：

Kim, Seung-Hoi ^{[1
]}

Rieke, Reuben D. ^{[1
]}

机构：

[1] Rieke Met Inc, Lincoln, NE 68521 USA

来源：

SYNTHETIC METALS | 2009年 / 159卷 / 17-18期

关键词：

Thienylmanganese halides; Poly(3-hexylthiophene); LIGHT-EMITTING-DIODES; POLYMERS; COMPLEXES; MANGANESE;

D O I：

10.1016/j.synthmet.2009.05.019

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

For the first time, thienyl manganese halides have been used for the synthesis of regioregular head-to-tail poly(3-hexylthiophene). A variety of conditions were examined, and the polymerization was successfully completed in the presence of Ni(dppe)Cl-2 at ambient temperature affording the title polymer in high yields with excellent regioregularity. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1900 / 1902

页数：3

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