Structural Analysis of Iron Mixed-Valence Complex (n-C3H7)4N[FeIIFeIII(dto)3](dto=C2O2S2) under High Pressure

被引：2

作者：

Itoi, Miho ^{[1
]}

Kida, Noriyuki ^{[2
]}

Chin-Lin ^{[1
]}

Koeda, Masahito ^{[1
]}

Kojima, Norimichi ^{[2
]}

Hedo, Masato ^{[1
]}

Uwatoko, Yoshiya ^{[1
]}

Kobayashi, Yoshihiko ^{[3
]}

Asai, Kichizo ^{[3
]}

Ohishi, Yasuo ^{[4
]}

Takta, Masaki ^{[4
,5
]}

机构：

[1] Univ Tokyo, Inst Solid State Phys, Chiba 2778581, Japan

[2] Univ Tokyo, Grad Sch Arts & Sci, Meguro Ku, Tokyo 1538902, Japan

[3] Univ Electrocommun, Dept Appl Phys & Chem, Tokyo 1828585, Japan

[4] Spring 8 JASRI, Sayou, Hyogo 6795148, Japan

[5] RIKEN, Sayou, Hyogo 6795148, Japan

来源：

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN | 2007年 / 76卷

关键词：

Mixed-valence complex; electron transfer; powder x-ray diffraction; pressure;

D O I：

10.1143/JPSJS.76SA.190

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Iron mixed-valence complex, (n-C3H7)(4)N[(FeFeIII)-Fe-II(dto)(3)] shows an electron-transfer between Fe(II) and Fe(III) ion accompanied by a spin transition, i.e. a charge-transfer (CT) phase transition at 122.4 K. The pressure dependence of CT phase transition is evaluated by a x-ray structural analysis under high pressure. We report the structural changes of the CT transition under high pressure.

引用

页码：190 / 191

页数：2

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