Synergistic extraction study of samarium(III) from chloride medium by mixtures of bis(2,4,4-trimethylpentyl)phosphinic acid and 8-hydroxyquinoline

被引：27

作者：

Wang, Xianglan ^{[1
]}

Du, Mo ^{[1
]}

Liu, Hui ^{[1
]}

机构：

[1] Wuhan Bioengn Inst, Dept Chem & Environm Engn, Wuhan 430415, Peoples R China

来源：

SEPARATION AND PURIFICATION TECHNOLOGY | 2012年 / 93卷

关键词：

Synergistic extraction; Samarium; Cyanex272; 8-Hydroxyquinoline; SOLVENT-EXTRACTION; RARE-EARTHS; MONO-2-ETHYLHEXYL ESTER; LANTHANIDE METALS; PHOSPHINIC ACID; ACETIC-ACID; SEPARATION; LANTHANUM(III); HEPTANE;

D O I：

10.1016/j.seppur.2012.03.002

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The extraction behavior of samarium(III) with mixtures of bis(2,4,4-trimethylpentyl) phosphinic acid (Cyanex272, H(2)A(2)) and 8-hydroxyquinoline (HQ) in heptane has been investigated from chloride medium. The mixtures are proved to have higher selectivity when applied to the extraction of the samarium compared with single extractant, the largest synergistic enhancement factor can be calculated to be 233 at pH 4.0. The results show that Sm3+ is extracted into heptane as Sm(OH)(2)Q(HA)(2(o)) or Sm(OH)(2)Q(HQ)(4)-(HA)(2(o)) with synergistic mixture. The equilibrium constants have been determined. The result shows that the synergistic extraction system not only shows perfect capacity of synergistic extraction, but also overcomes emulsification of 8-hydroxyquinoline. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：48 / 51

页数：4

共 50 条

[41] Extraction of molybdenum with bis(2,4,4-trimethylpentyl)phosphine acid (Cyanex-272)
Knyaz'kina, O. V.
Kuznetsova, G. G.
Travkin, V. F.
Vol'dman, G. M.
Glubokov, Yu. M.
RUSSIAN JOURNAL OF NON-FERROUS METALS, 2010, 51 (06) : 451 - 456
[42] Extraction of molybdenum with bis(2,4,4-trimethylpentyl)phosphine acid (Cyanex-272)
O. V. Knyaz’kina
G. G. Kuznetsova
V. F. Travkin
G. M. Vol’dman
Yu. M. Glubokov
Russian Journal of Non-Ferrous Metals, 2010, 51 : 451 - 456
[43] Adsorption of heavy rare earth(III) with extraction resin containing bis(2,4,4-trimethylpentyl) monothiophosphinic acid
Jia, Q
Wang, ZH
Li, DQ
Niu, CJ
JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 374 (1-2) : 434 - 437
[44] Solvent extraction separation of antimony(III) and bismuth(III) with bis (2,4,4-trimethylpentyl) monothiophosphinic acid (Cyanex 302)
Sarkar, SG
Dhadke, PM
SEPARATION AND PURIFICATION TECHNOLOGY, 1999, 15 (02) : 131 - 138
[45] Liquid-Liquid Extraction and Separation of Co(II) and Ni(II) from Chloride Medium by bis(2,4,4-trimethylpentyl) dithiophosphinic acid in Kerosene
Negm, M. A.
El-Said, N.
El-Didamony, H.
Daoud, J. A.
ARAB JOURNAL OF NUCLEAR SCIENCES AND APPLICATIONS, 2012, 45 (03): : 26 - 34
[46] Extraction and spectrophotometric determination of copper(II) with bis(2,4,4-trimethylpentyl)dithiophosphinic acid
Argekar, AP
Shetty, AK
ANALYTICAL SCIENCES, 1996, 12 (02) : 255 - 258
[47] EXTRACTION MECHANISM OF SC(III) AND SEPARATION FROM TH(IV),FE(III) AND LU(III) WITH BIS(2,4,4-TRIMETHYLPENTYL)PHOSPHINIC ACID IN N-HEXANE FROM SULFURIC-ACID-SOLUTIONS
WANG, C
LI, DQ
SOLVENT EXTRACTION AND ION EXCHANGE, 1994, 12 (03) : 615 - 631
[48] Nickel(II) Extraction from Sulphate Media with Bis (2,4,4-Trimethylpentyl)Dithiophosphinic Acid Dissolved in Nonane
Pashkov, G. L.
Grigorieva, N. A.
Pavlenko, N. I.
Fleitlikh, I. Yu.
Nikiforova, L. K.
Pleshkov, M. A.
SOLVENT EXTRACTION AND ION EXCHANGE, 2008, 26 (06) : 749 - 763
[49] Zinc(II) extraction from phosphoric media by bis(2,4,4-trimethylpentyl)-dithiophosphinic acid (CYANEX 301)
Ocio, A
Elizalde, MP
SOLVENT EXTRACTION AND ION EXCHANGE, 2003, 21 (02) : 259 - 271
[50] Co(II) and Ni(II) transport from model and real sulfate solutions by extraction with bis(2,4,4-trimethylpentyl)phosphinic acid (Cyanex 272)
Stefaniak, Jakub
Karwacka, Sara
Janiszewska, Malgorzata
Dutta, Abhishek
Rene, Eldon R.
Regel-Rosocka, Magdalena
CHEMOSPHERE, 2020, 254

← 1 2 3 4 5 →