Synthesis of Prenylarenes and Related (Multisubstituted Allyl)arenes from Aryl Halides and Homoallyl Alcohols via Palladium-Catalyzed Retro-Allylation

被引：17
|
作者：
Iwasaki, Masayuki [1 ]
Yorimitsu, Hideki [1 ]
Shima, Koichiro [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Nishikyo Ku, Kyoto 6158510, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2009年 / 82卷 / 02期
关键词：
CROSS-COUPLING REACTIONS; ORGANIC-SYNTHESIS; PHOTOSUBSTITUTION; DICYANOBENZENES;
D O I：
10.1246/bcsj.82.249
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reactions of aryl halides with 2,3,3-trimethyl-4-penten-2-ol in the presence of a palladium catalyst result in prenyl transfer from the alcohol to aryl halides via retro-allylation, yielding prenylarenes. Other multisubstituted allyl groups such as the 2,3-dimethyl-2-butenyl group are introduced to aromatic rings.
引用
收藏
页码：249 / 253
页数：5
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