Gold(I)-catalyzed domino cyclization for the synthesis of polyaromatic heterocycles

被引：9
|
作者：
Morin, Mathieu [1 ]
Levesque, Patrick [1 ]
Barriault, Louis [1 ]
机构：
[1] Univ Ottawa, Dept Chem, Ctr Catalysis Res & Innovat, Ottawa, ON K1T 1B5, Canada
来源：
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 9卷
基金：
加拿大自然科学与工程研究理事会;
关键词：
GOLD-CATALYZED REACTIONS; CYCLOADDITIONS; ARYLALKYNES; 1,3-ENYNES; CARBENES; ALKENES;
D O I：
10.3762/bjoc.9.297
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Gold(I) complexes have emerged as powerful and useful catalysts for the formation of new C-C, C-O and C-N bonds. Taking advantage of the specificity of [IPrAuNCMe][SbF6] complexes to favor the 5-exo-dig cyclization over the 6-endo-dig pathway, we report a high yielding and efficient method to generate substituted polyaromatic heterocycles under remarkably mild reaction conditions.
引用
收藏
页码：2625 / 2628
页数：4
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