Synthesis, crystal structures and mesomorphic properties of liquid crystals with a N, N′-Bis(tropon-2-yl)piperazine skeleton

被引:7
|
作者
Yamamoto, E
Kubo, K [1 ]
Mori, A
Ujiie, S
机构
[1] Kyushu Univ 86, Inst Adv Mat Study, Fukuoka 8168580, Japan
[2] Kyushu Univ 39, Grad Sch Engn Sci, Fukuoka 8168580, Japan
[3] Shimane Univ, Interdisciplinary Fac Sci & Engn, Dept Mat Sci, Matue 6908504, Japan
关键词
D O I
10.1246/cl.2002.100
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New troponoid liquid crystals with a N, N'-bis(tropon-2-yl)piperazine core were prepared. N, N'-Bis(tropon-2-yl)piperazine derivatives (1) had a smectic C phase with lower thermal stabilities than the corresponding benzenoid derivatives (2), which had a smectic B phase. A single crystal of 1d had distinct layer structures observed in a smectic C phase.
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页码:100 / 101
页数:2
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