A high yielding, one-pot, triton-B catalyzed synthesis of dithiocarbamates using alcoholic tosylates

被引：29
|
作者：
Chaturvedi, Devdutt [1 ]
Ray, Suprabhat [1 ]
机构：
[1] Cent Drug Res Inst, Mat & Proc Chem Div, Lucknow 226001, Uttar Pradesh, India
来源：
MONATSHEFTE FUR CHEMIE | 2006年 / 137卷 / 04期
关键词：
triton-B; carbon disulfide; alcoholic tosylates; dithiocarbamates; thiocarbamation;
D O I：
10.1007/s00706-005-0460-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel process for the one-step chemoselective conversion of alcoholic tosylates into. dithiocarbamates as protected amines was developed using benzyltlimethylammoniumhydroxide (Triton-B) in presence of carbon disulfide. Thus, dithiocarbamates of different amines were prepared in very good to excellent yields. This protocol is mild, chemoselective, and efficient compared to other reported methods.
引用
收藏
页码：465 / 469
页数：5
相关论文
共 50 条
  • [1] A High Yielding, One-Pot, Triton-B Catalyzed Synthesis of Dithiocarbamates Using Alcoholic Tosylates
    Devdutt Chaturvedi
    Suprabhat Ray
    [J]. Monatshefte für Chemie / Chemical Monthly, 2006, 137 : 465 - 469
  • [2] Triton-B catalyzed, efficient, one-pot synthesis of carbamate esters from alcoholic tosylates
    Chaturvedi, Devdutt
    Ray, Suprabhat
    [J]. MONATSHEFTE FUR CHEMIE, 2006, 137 (04): : 459 - 463
  • [3] Triton-B Catalyzed, Efficient, One-Pot Synthesis of Carbamate Esters from Alcoholic Tosylates
    Devdutt Chaturvedi
    Suprabhat Ray
    [J]. Monatshefte für Chemie / Chemical Monthly, 2006, 137 : 459 - 463
  • [4] Triton-B catalyzed, efficient one-pot synthesis of dithiocarbazates
    Chaturvedi, Devdutt
    Mishra, Nisha
    Mishra, Virendra
    [J]. MONATSHEFTE FUR CHEMIE, 2008, 139 (09): : 1033 - 1036
  • [5] Triton-B catalyzed, efficient one-pot synthesis of carbazates
    Devdutt Chaturvedi
    Amit K. Chaturvedi
    Nisha Mishra
    Virendra Mishra
    [J]. Monatshefte für Chemie - Chemical Monthly, 2008, 139 : 1463 - 1466
  • [6] Triton-B catalyzed, efficient one-pot synthesis of dithiocarbazates
    Devdutt Chaturvedi
    Nisha Mishra
    Virendra Mishra
    [J]. Monatshefte für Chemie - Chemical Monthly, 2008, 139 : 1033 - 1036
  • [7] Triton-B catalyzed, efficient one-pot synthesis of carbazates
    Chaturvedi, Devdutt
    Chaturvedi, Amit K.
    Mishra, Nisha
    Mishra, Virendra
    [J]. MONATSHEFTE FUR CHEMIE, 2008, 139 (12): : 1463 - 1466
  • [8] Triton-B-Catalyzed, Efficient, One-Pot Synthesis of Dithiocarbazates Through Alcoholic Tosylates
    Chaturvedi, Devdutt
    Mishra, Nisha
    Chaturvedi, Amit K.
    Mishra, Virendra
    [J]. SYNTHETIC COMMUNICATIONS, 2009, 39 (07) : 1273 - 1281
  • [9] Triton-B-Catalyzed, Efficient, One-Pot Synthesis of Carbazates Through Alcoholic Tosylates
    Chaturvedi, Devdutt
    Chaturvedi, Amit K.
    Mishra, Nisha
    Mishra, Virendra
    [J]. SYNTHETIC COMMUNICATIONS, 2008, 38 (22) : 4013 - 4022
  • [10] A High Yielding, One-Pot, Triton-B Catalyzed, Expeditious Synthesis of Carbamate Esters by Four Component Coupling Methodology
    Devdutt Chaturvedi
    S. Ray
    [J]. Monatshefte für Chemie / Chemical Monthly, 2006, 137 : 201 - 206
12345