Strategies for the Immobilization of Homogeneous Catalysts and Their Use in the Synthesis of Carbamates

被引：18

作者：

Orejon, Aranzazu ^{[1
]}

Masdeu-Bulto, Anna M. ^{[1
]}

Salagre, Pilar ^{[1
]}

Castillon, Sergio ^{[2
]}

Claver, Carmen ^{[1
]}

Padilla, Ana ^{[3
]}

Almena, Beatriz ^{[3
]}

Luis Serrano, Francisco ^{[3
]}

机构：

[1] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43007, Spain

[2] Univ Rovira & Virgili, Dept Quim Analit & Organ, Tarragona 43007, Spain

[3] Ctr Tecnol Repsol YPF, Madrid 28931, Spain

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2008年 / 47卷 / 21期

关键词：

D O I：

10.1021/ie8002599

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Different methods of immobilization of N,N'-bis(salicylidene)ethylenediaminocobalt(II), [Co(salen)] complex, using K10 montmorillonite and silica have been used. These supported catalysts are active in the oxidative carbonylation of aniline using NaI as a promoter. The principal products obtained are N,N'-diphenylurea and I 1-butyl-N-phenylcarbamate.

引用

页码：8032 / 8036

页数：5

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