The crystal structure of PbFe[AsO4][AsO3(OH)]

被引：4
|
作者：
Effenberger, H
Hejny, C
Pertlik, F
机构：
[1] Inst. F. Mineral. und Kristal., Universität Wien
来源：
MONATSHEFTE FUR CHEMIE | 1996年 / 127卷 / 02期
关键词：
PbFe[AsO4][AsO3(OH); synthesis; hydrothermal; crystal structure; crystal chemistry;
D O I：
10.1007/BF00807393
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Light green to nearly colourless crystals of PbFe[AsO4] [AsO3(OH)] were synthesized under moderate hydrothermal conditions (a = 4.846(2), b = 8.482(4), c = 15.560(6)Angstrom beta = 92.82(3)degrees, space group P2(1)/n, Z = 4). For a single-crystal structure determination, 110 variable parameters were refined to R = 0.042, R(w) = 0.031 (1545 X-ray reflections with F-0 > 3 sigma(F-0) and sin theta/lambda less than or equal to 70 degrees). The crystal structure is characterized by a three-dimensional corner-connection of the FeO6 octahedra with the arsenate tetrahedra and the protonated arsenate groups. Each two PbO7 polyhedra are edge-connectedto Pb2O12 dimers which are located within interstitial holes.
引用
收藏
页码：127 / 133
页数：7
相关论文
共 50 条
  • [31] THE CRYSTAL STRUCTURE OF VLADIMIRITE, WITH A REVISED CHEMICAL FORMULA, Ca4(AsO4)2(AsO3OH)•4H2O
    Yang, Hexiong
    Evans, Stanley H.
    Downs, Robert T.
    Jenkins, Robert A.
    [J]. CANADIAN MINERALOGIST, 2011, 49 (04): : 1055 - 1064
  • [32] THE CRYSTAL-STRUCTURE OF AUSTINITE, CAZN(ASO4)(OH), FROM KAMAREZA, LAURION (GREECE)
    GIUSEPPETTI, G
    TADINI, C
    [J]. NEUES JAHRBUCH FUR MINERALOGIE-MONATSHEFTE, 1988, (04): : 159 - 166
  • [33] Crystal structure of Zn2(HTeO3)(AsO4)
    Eder, Felix
    Weil, Matthias
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 : 555 - +
  • [34] Synthesis and crystal structure of Na3NbO(AsO4)2
    Hizaoui, K
    Jouini, N
    Jouini, T
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1999, 144 (01) : 53 - 61
  • [35] Crystal Structure of the Arsenate(V) NaTi2[AsO4]3
    Ben Yahia, Hamdi
    Rodewald, Ute Ch.
    Poettgen, Rainer
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2010, 65 (05): : 639 - 642
  • [36] The crystal structure of johnbaumite, Ca5(AsO4)3OH, the arsenate analogue of hydroxylapatite
    Biagioni, Cristian
    Pasero, Marco
    [J]. AMERICAN MINERALOGIST, 2013, 98 (8-9) : 1580 - 1584
  • [37] Spectroscopic and magnetic properties of the MNi(AsO4) (M = Li, Na) arsenates and crystal structure refinement of LiNi(AsO4)
    Mesa, JL
    Pizarro, JL
    Lezama, L
    Escobal, J
    Arriortua, MI
    Rojo, T
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1998, 141 (02) : 508 - 513
  • [38] The molecular structure of the mineral beudantite PbFe3(AsO4,SO4)2(OH)6 - Implications for arsenic accumulation and removal
    Frost, Ray L.
    Palmer, Sara J.
    Spratt, Henry J.
    Martens, Wayde N.
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2011, 988 (1-3) : 52 - 58
  • [39] CRYSTAL STRUCTURE OF W2O3(ASO4)2
    WESTERLU.M
    [J]. ACTA CHEMICA SCANDINAVICA, 1971, 25 (04): : 1429 - &
  • [40] CRYSTAL CHEMISTRY OF BASIC MANGANESE ARSENATES .3. CRYSTAL STRUCTURE OF EVEITE MN2(OH) (ASO4)
    MOORE, PB
    SMYTH, JR
    [J]. AMERICAN MINERALOGIST, 1968, 53 (11-1) : 1841 - &
12345