Iridium-catalyzed asymmetric reductive amination of ketones using an amidophosphite ligand

被引：1
|
作者：
Lyubimov, S. E. [1 ]
Ozolin, D. V. [1 ]
Ivanov, P. Yu. [1 ]
Maiorov, K. B. [2 ]
Velezheva, V. S. [1 ]
Davankov, V. A. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
[2] Cent TB Res Inst, Moscow 107564, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2015年 / 64卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
asymmetric reductive amination; iridium compounds; amidophosphites; biologically active compounds; HYDROGENATION;
D O I：
10.1007/s11172-015-0861-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A direct iridium-catalyzed asymmetric reductive amination of ketones using an amidophosphite ligand was accomplished for the first time. A new one-step approach to the preparation of biologically active pyrazinocarbazoles was developed.
引用
收藏
页码：318 / 321
页数：4
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