Synthesis of 8-Methyl-5-[(methylsulfanyl)methyl]-3-thiabicyclo[3.3.1]non-7-en-6-one and Its Extraction Ability for Gold(III)

被引：1
|
作者：
Golubyatnikova, L. G. [1 ]
Khisamutdinov, R. A. [1 ]
Baeva, L. A. [1 ]
Murinov, Yu. I. [1 ]
机构：
[1] Russian Acad Sci, Ufa Inst Chem, Subdiv Ufa Fed Res Ctr, Pr Oktyabrya 69, Ufa 450054, Bashkortostan, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2018年 / 88卷 / 12期
关键词：
8-methyl-5-[(methylsulfanyl)methyl]-3-thiabicyclo[3; 3; 1]non-7-en-6-one; gold(III); extraction; concentration; complex formation; THIOALKYLATION REACTION; KETONES;
D O I：
10.1134/S1070363218120113
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient one-pot procedure has been proposed for the synthesis of 8-methyl-5-[(methylsulfanyl) methyl]-3-thiabicyclo[3.3.1]non-7-en-6-one from accessible natural raw materials. A stable complex of the title compound with gold(III) has been obtained by the extraction method, and the mode of its coordination to the metal ion has been determined by IR and NMR spectroscopy.
引用
收藏
页码：2524 / 2527
页数：4
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