Synthesis, crystal and molecular structure of 1,3-bis[5-(3-methylisoxazolino-2)]-1,1,3,3-tetraphenyldisiloxane

被引：0

作者：

Lukevics, E ^{[1
]}

Dirnens, V ^{[1
]}

Arsenyan, P ^{[1
]}

Popelis, J ^{[1
]}

Kemme, A ^{[1
]}

机构：

[1] LATVIAN INST ORGAN SYNTH,RIGA 1006,LATVIA

来源：

MAIN GROUP METAL CHEMISTRY | 1996年 / 19卷 / 03期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The addition of acetonitrile oxide to 1,3-divinyl-1,1,3,3-tetraphenyldisiloxane affords 1,3-bis[5-(3-methylisoxazolino-2)]-1,1,3,3-tetraphenyldisiloxane, the latter exists as a mixture of R,S- and R,R-diastereoisomers. The bond angle of Si-O-Si fragment in R,S-isomer equals 180(0)degrees and in R,R-isomer it is 172.8(2)degrees.

引用

页码：167 / 174

页数：8

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