Peripherally tetra-{2-(2,3,5,6-tetrafluorophenoxy)ethoxy} substituted cobalt(II), iron(II) metallophthalocyanines: Synthesis and their electrochemical, catalytic activity studies

被引：25

作者：

Kamiloglu, Ayse Aktas ^{[1
]}

Acar, Irfan ^{[2
]}

Biyiklioglu, Zekeriya ^{[1
]}

Saka, Ece Tugba ^{[1
]}

机构：

[1] Karadeniz Tech Univ, Dept Chem, Fac Sci, TR-61080 Trabzon, Turkey

[2] Karadeniz Tech Univ, Fac Technol, Dept Energy Syst Engn, TR-61830 Trabzon, Turkey

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 828卷

关键词：

Phthalocyanine; Cobalt; Iron; Cyclic voltammetry; Electrochemistry; Benzyl alcohol; HIGHLY SELECTIVE OXIDATION; AGGREGATED SILICON PHTHALOCYANINES; METAL-FREE; ZINC PHTHALOCYANINES; CARBONYL-COMPOUNDS; BENZYL ALCOHOL; SPECTROSCOPIC CHARACTERIZATION; FUNCTIONALIZED GRAPHENE; BEARING; CO(II);

D O I：

10.1016/j.jorganchem.2016.11.022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this study, new electron-withdrawing peripherally tetra {2-[2,3,5,6-tetrafluorophenoxylethoxy} groups substituted CO (II) Pc and Fe-II Pc have been synthesized for the first time and their structures have been characterized by using IR, H-1 NMR, mass and UV Vis spectroscopy techniques. Electrochemical properties of Fe-II Pc and Co-II Pc were investigated by using cyclic voltammetry (CV) and square wave voltammetry (SWV) techniques. Voltammetric analyses of phthalocyanines supported the proposed structure of the synthesized complexes. Iron and cobalt phthalocyanines showed metal and ligand based reduction reactions as expected. Also Co(II) and Fe(II) phthalocyanine complexes (1,2) were examined as a catalyst for the oxidation of benzyl alcohol with changing different parameters to determine the optimal conditions. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：59 / 67

页数：9

共 50 条

[41] MAGNETIC AND SPECTRAL STUDIES ON COPPER(II), NICKEL(II), COBALT(II), IRON(III) AND MANGANESE(II) COMPLEXES OF 3-BROMO-2-HYDROXY-5-METHYL ACETOPHENONE HYDRAZONE
LAL, K
MALHOTRA, SR
REVUE ROUMAINE DE CHIMIE, 1985, 30 (05) : 395 - 400
[42] Synthesis, Structure, and Biological Activity of Coordination Compounds of Cobalt(II), Nickel(II), and Copper(II) with N-(Methoxyphenyl)-2-[(5-nitrofuryl)methylene]hydrazine Carbothioamides
A. P. Gulea
N. L. Mitkevich
Yu. M. Chumakov
P. A. Petrenko
G. G. Balan
O. S. Burduniuc
V. I. Tsapkov
Russian Journal of General Chemistry, 2019, 89 : 1415 - 1423
[43] Synthesis, Structure, and Biological Activity of Coordination Compounds of Cobalt(II), Nickel(II), and Copper(II) with N-(Methoxyphenyl)-2-[(5-nitrofuryl)methylene]hydrazine Carbothioamides
Gulea, A. P.
Mitkevich, N. L.
Chumakov, Yu. M.
Petrenko, P. A.
Balan, G. G.
Burduniuc, O. S.
Tsapkov, V. I.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2019, 89 (07) : 1415 - 1423
[44] Synthesis, characterization, photophysical and photochemical properties of peripherally tetra-1,2,4-triazol-3-ylthio substituted metal-free phthalocyanine and its zinc(II) and lead(II) derivatives
Demirbas, Umit
Yanik, Hulya
Akcay, Hakki Turker
Durmus, Mahmut
Bekircan, Olcay
Kantekin, Halit
JOURNAL OF COORDINATION CHEMISTRY, 2022, 75 (3-4) : 448 - 456
[45] The synthesis and characterization of mixed ligand Ru(II) complexes with dipyrido(2,3-a:3′,2′-j) phenazine (dpop′) and 2,3,5,6-tetra(2-pyridyl)-pyrazine (tppz)
Ruminski, Ronald R.
Aasen, Tyler D.
INORGANICA CHIMICA ACTA, 2010, 363 (05) : 905 - 910
[46] Synthesis, characterization and electrical properties of novel metal-free, Co(II), Cu(II), Fe(II), Mn(II), Sn(II) phthalocyanines peripherally tetra-substituted with 2,3-dihydro-1H-inden-5-yloxy moiety
Odabas, Zafer
Altindal, Ahmet
Bulut, Mustafa
SYNTHETIC METALS, 2011, 161 (15-16) : 1742 - 1752
[47] Coordination Modes of a Schiff Base Derived from Substituted 2-Aminothiazole with Chromium(III), Manganese(II), Iron(II), Cobalt(II), Nickel(II) and Copper(II) Metal Ions: Synthesis, Spectroscopic and Antimicrobial Studies
Thakar, Ambit
Joshi, Krishnakant
Pandya, Kishor
Pancholi, Arvind
E-JOURNAL OF CHEMISTRY, 2011, 8 (04) : 1750 - 1764
[48] SYNTHESIS AND CRYSTAL-STRUCTURE OF [N,N'-BIS(2,3,5,6-TETRAFLUOROPHENYL)-ETHANE-1,2-DIAMINATO(2-)]DIPYRIDINEPLATINUM(II)
DEACON, GB
GATEHOUSE, BM
GRAYSON, IL
NESBIT, MC
POLYHEDRON, 1984, 3 (06) : 753 - 755
[49] STUDIES ON THE ELECTROCHEMICAL-BEHAVIOR OF 2-(3,5-DIBROMO-2-PYRIDYL)AZO-5-DIETHYLAMINOPHENOL-CO(II) COMPLEX IN THE PRESENCE OF NITRITE - TRACE MEASUREMENTS OF COBALT
ZHAO, ZF
CAI, XH
PEI, JH
ZHANG, YM
ZHOU, XY
ELECTROANALYSIS, 1991, 3 (09) : 949 - 954
[50] SYNTHESIS, CHARACTERIZATION AND FUNGITOXICITY OF MANGANESE(II), IRON(II), COBALT(II), NICKEL(II), COPPER(II) AND ZINC(II) COMPLEXES OF N-PHENYL-5-PHENYL-1,3,4-OXADIAZOLE-2-SULFONAMIDE AND 5-PHENYL-1,3,4-OXADIAZOLE-2-IMINO SULFONAMIDE
SINGH, H
SRIVASTAVA, VK
SHUKLA, SN
SRIVASTAVA, MK
UPADHYAY, MK
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1994, 33 (04): : 350 - 353

← 1 2 3 4 5 →