Synthesis and structure of the niobium complexonate [Nb2S4(Py(COO)2)2(H2O)2] • 3H2O

被引：0

作者：

Sokolov, MN ^{[1
]}

Geras'ko, OA ^{[1
]}

Virovets, AV ^{[1
]}

Fedorov, VE ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 1998年 / 24卷 / 11期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Nb2S4(Py(COO)(2))(2)(H2O)(2)] . 3H(2)O was synthesized and studied by X-ray diffraction analysis. The crystals are monoclinic, space group P2(1)/n, a = 21.075(2), b = 11.203(1), c = 21.749(2) Angstrom, beta = 1 10.631(9)degrees, V = 4805.7(8) Angstrom(3), Z = 8. The structure contains two crystallographically independent types of molecules having identical structure and close geometric parameters. The complex synthesized is the first structurally characterized niobium complexonate.

引用

页码：775 / 780

页数：6

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