Synthesis and structure of the niobium complexonate [Nb2S4(Py(COO)2)2(H2O)2] • 3H2O

被引：0
|
作者：
Sokolov, MN [1 ]
Geras'ko, OA [1 ]
Virovets, AV [1 ]
Fedorov, VE [1 ]
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 1998年 / 24卷 / 11期
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D O I：
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex [Nb2S4(Py(COO)(2))(2)(H2O)(2)] . 3H(2)O was synthesized and studied by X-ray diffraction analysis. The crystals are monoclinic, space group P2(1)/n, a = 21.075(2), b = 11.203(1), c = 21.749(2) Angstrom, beta = 1 10.631(9)degrees, V = 4805.7(8) Angstrom(3), Z = 8. The structure contains two crystallographically independent types of molecules having identical structure and close geometric parameters. The complex synthesized is the first structurally characterized niobium complexonate.
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页码：775 / 780
页数：6
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