Yttria promoted metallic nickel catalysts for the partial oxidation of methane to synthesis gas

被引:22
|
作者
Wang, Yaquan [1 ]
Hong, Xuebin [1 ]
Li, Bingbing [1 ]
Wang, Wenju [1 ]
Wang, Dalin [1 ]
机构
[1] Tianjin Univ, Key Lab Green Chem Technol, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
来源
JOURNAL OF NATURAL GAS CHEMISTRY | 2008年 / 17卷 / 04期
基金
国家高技术研究发展计划(863计划);
关键词
metallic nickel; yttria; catalytic partial oxidation of methane; syngas;
D O I
10.1016/S1003-9953(09)60006-2
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A metallic Ni catalyst was prepared with nickel sponge, followed by acid treatment. It was further promoted with yttria by an impregnation method. The catalysts were characterized by SEM, BET, XRD, TPR, XPS. etc., and Studied in the partial oxidation of methane to syngas. The characterization results showed that the yttria promoted metallic Ni catalysts had high specific Surface area and more NiO. The reaction results showed Thai the yttria promoter increased the CH(4) conversion and the selectivity for H(2), and CO.
引用
收藏
页码:344 / 350
页数:7
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