Bis(phenylenedithio)tetrathiafulvalene (BPhDT-TTF): Synthesis and properties of a new pi-donor for organic metals

被引：2
|
作者：
Muller, H
Fiedler, S
Saad, M
Riekel, C
机构：
来源：
SYNTHETIC METALS | 1997年 / 86卷 / 1-3期
关键词：
heterocycle synthesis; electrocrystallisation; organic conductor;
D O I：
10.1016/S0379-6779(97)80952-6
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The new pi-donor bis(phenylenedithio)tetrathiafulvalene (7), synthesized via phosphite coupling of 2-oxo-1,3-dithiolo[4,5 b][1,4]benzodithiin (6) has been prepared in five steps starting from dimercaptobenzene (1) and chloroactyl chloride (2). Spectroscopic and electrochemical data of 7 are presented. Electrocrystallization yielded highly conducting radical cation salts (sigma(RT)=100 S/cm) as fibers (typical dimensions: 10000x50x20 mu m). Structural aspects, obtained on these salts by microdiffraction techniques, will be discussed.
引用
收藏
页码：1885 / 1886
页数：2
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