Preparation of disperse dye/latex dispersion for printing of cellulose fabric

被引:10
|
作者
Fu, Shaohai [1 ]
Lu, Jianhui [1 ]
Lu, Xiaoying [2 ]
Bai, Fushun [1 ]
机构
[1] Jiangnan Univ, Minist Educ, Key Lab Ecotext, Wuxi 214122, Jiangsu, Peoples R China
[2] Gemei Sci & Technol Corp, Nantong 215337, Jiangsu, Peoples R China
关键词
Disperse dye/latex composite; Dispersion; Cellulose fabric; Printing; Miniemulsion polymerization; Polymerizable emulsifier; MINIEMULSION POLYMERIZATION; COTTON; DYE; ENCAPSULATION; INK;
D O I
10.1016/j.colsurfa.2013.01.037
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A dispersion was prepared from disperse dye and latex composite (disperse dye/latex composite) by the method of miniemulsion polymerization. Different types of costabilizers, emulsifiers and initiators were tested for optimizing miniemulsion polymerization which was critical to achieve high-performance dispersion for printing of cellulosic fabric. Experimental results showed that hexadecane (HD), allyloxy nonylphenol polyoxyethylene ether ammonium sulfate (DNS-86) and ammonium persulfate (APS) were suitable for use as costabilizer, emulsifier and initiator in miniemulsion polymerization. An optimal dispersion was obtained by using 14.4 mmol L-1 DNS-86, a 1:100 mass ratio of HD to styrene and a 7.5:100 mass ratio of APS to styrene. Fourier-transform infrared spectroscopy (FTIR) suggested that copolymerization took place between DNS-86 and styrene. Transmission electron microscopy (TEM) showed that the spherical particles were formed and uniformly distributed in the dispersion. Printing cellulose fabric with the disperse dye/latex composite produced higher color strength and color fastness than the original disperse dye. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:131 / 138
页数:8
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