Structure, electrical properties and depolarization temperature of (Bi0.5Na0.5)TiO3-BaTiO3 lead-free piezoelectric ceramics

Lead-free ceramics (1 - x)Bi0.5Na0.5TiO3-xBaTiO(3) have been prepared by a conventional solid reaction method, and their structure, electrical properties and depolarization temperature have been studied. The results of X-ray diffraction reveal that Ba2+ diffuse into the Bi0.5Na0.5 TiO3 lattices to form a solid solution with a pure perovskite structure, and a morphotropic phase boundary (MPB) exists at 0.06 < x < 0.10. The grain size decreases with x. After the introduction of BaTiO3 into Bi0.5Na0.5TiO3, the ceramics exhibit a lower coercive field E-c and a larger remanent polarization P-r. Because of the strong ferroelectricity and MPB, the ceramics with x = 0.06 exhibit optimum piezoelectric properties: d(33) = 155 pC/N and k(P) = 36.7%. The depolarization temperature T-d shows a strong compositional dependence and gives a minimum value at MPB. In addition, the ceramics exhibit relaxor characteristic, which probably results from the cation disordering in the 12-fold coordination sites. The results of the ferroelectric and dielectric properties at high temperatures may suggest that the ceramics may contain both the polar and non-polar regions at temperatures above T-d. (C) 2007 Elsevier Masson SAS. All rights reserved.