Static light scattering measurements along a critical decomposition line of a ternary liquid mixture

被引:4
|
作者
Müller, O [1 ]
Winkelmann, J [1 ]
机构
[1] Univ Halle Wittenberg, Inst Phys Chem, D-06217 Merseburg, Germany
来源
PHYSICAL REVIEW E | 1999年 / 60卷 / 04期
关键词
D O I
10.1103/PhysRevE.60.4453
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
In the present paper we publish results of static light scattering measurements in the ternary system N,N-dimetylformamide+n-heptane+toluene. We determined the critical decomposition line in a concentration range of 0 up to 25 mole-% toluene. In seven mixtures along this line we obtained the correlation length of fluctuations and the generalized osmotic susceptibility as a function of the temperature. We apply simple, power laws to calculate the critical exponents of both properties. The determined exponents show a systematic growth if the fraction of the third component increases. This growth exceeds the values for critical exponents that were predicted by the critical exponent renormalization. [S1063-651X(99)09810-4].
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页码:4453 / 4459
页数:7
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