Efficient N-heterocyclic carbene nickel pincer complexes catalyzed cross coupling of benzylic ammonium salts with boronic acids

被引：15
|
作者：
Liu, Xi-Yu [1 ]
Zhu, Hai-Bo [1 ]
Shen, Ya-Jing [1 ]
Jiang, Jian [1 ]
Tu, Tao [1 ,2 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2017年 / 28卷 / 02期
基金：
中国国家自然科学基金; 国家教育部博士点专项基金资助;
关键词：
N-Heterocyclic carbene; Nickel; Cross coupling; Benzylic ammonium salts; Boronic acid; MOLECULAR-MASS GELATORS; ARYLBORONIC ACIDS; STEREOSPECIFIC FORMATION; GRIGNARD-REAGENTS; BOND ACTIVATION; AGGREGATION; HALIDES; RECOGNITION; PHOSPHATES; ALCOHOLS;
D O I：
10.1016/j.cclet.2016.09.006
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Pyridine-bridged bis-benzimidazolylidene nickel complexes exhibited very high catalytic activity toward cross coupling of inactive (hetero)aryl benzylic ammonium salts with (hetero)aryl and alkenyl boronic acids under mild reaction conditions. Even at 2 mol% catalyst loading, a wide range of substrates for both coupling partners with different steric and electronic properties were well tolerated. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：350 / 353
页数：4
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