Catalytic dealkylation of phosphates with binuclear boron compounds

被引：38
|
作者：
Keizer, TS [1 ]
De Pue, LJ [1 ]
Parkin, S [1 ]
Atwood, DA [1 ]
机构：
[1] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 09期
关键词：
D O I：
10.1021/ja017360m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Salen(tBu) ligand and its derivatives were used to prepare binuclear boron complexes. These compounds have the formula, L(BBr2)2 (L = Salpen(tBu) and Salben(tBu)). These are formed from the reaction of the corresponding L[B(OMe)2]2 with BBr3. They represent a new type of binuclear boron compound. These compounds are active towards the dealkylation of many phosphates. They are also catalytically active with a stoichiometric amount of BBr3 to trimethylphosphate. Copyright © 2002 American Chemical Society.
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收藏
页码：1864 / 1865
页数：2
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