Universal ion exchange method for flowerlike metal telluride (PbTe, CdTe, Sb2Te3, Bi2Te3, and Cu7Te4) microstructures by using -ZnTe(en)0.5 as templates

被引：1

作者：

Xu, Weiwei ^{[1
,2
]}

Tian, Guimin ^{[1
]}

Ma, Xiaohua ^{[3
]}

Li, Hui ^{[1
]}

Niu, Jinzhong ^{[1
]}

机构：

[1] Henan Inst Engn, Coll Sci, Zhengzhou 451191, Henan, Peoples R China

[2] Henan Univ, Minist Educ, Key Lab Special Funct Mat, Kaifeng 475004, Peoples R China

[3] China Tobacco Henan Ind Co Ltd, Golden Leaf Prod & Mfg Ctr, Zhengzhou 450000, Henan, Peoples R China

来源：

MICRO & NANO LETTERS | 2019年 / 14卷 / 01期

关键词：

zinc compounds; semiconductor growth; cadmium compounds; crystal growth from solution; X-ray diffraction; lead compounds; II-VI semiconductors; IV-VI semiconductors; nanostructured materials; organic-inorganic hybrid materials; ion exchange; metal telluride microcrystals; 3D metal telluride microstructures; universal ion exchange method; flowerlike metal telluride; universal ion exchange template-assisted route; three-dimensional metal telluride; metal ions; organic-inorganic hybrid; ethylenediamine molecules; time; 0; 5; as; 3; d; PbTe; Cu7Te4; CdTe; Sb2Te3; Bi2Te3; ZnTe; ZNSE; NANOSTRUCTURES; NANOWIRES; SINGLE; STEP;

D O I：

10.1049/mnl.2018.5209

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A universal ion exchange template-assisted route is successfully developed for preparing various three-dimensional (3D) metal telluride flowerlike microstructures, including PbTe, CdTe, Bi2Te3, Sb2Te3, and Cu7Te4. The proposed synthesis method is simple and reproducible. Firstly, organic-inorganic hybrid -ZnTe(en)(0.5) flowerlike microcrystals are prepared as the template, and then a corresponding metal salt (Pb, Cd, Bi, Sb, and Cu) is introduced to synthesise the corresponding metal telluride flowerlike microstructures. During this process, ethylenediamine molecules and Zn ions in the -ZnTe(en)(0.5) flowerlike microcrystals simultaneously exchange with metal ions (Pb, Cd, Bi, Sb, and Cu) after the addition of metal precursors, and finally form flowerlike metal telluride microcrystals. This method may be further extended for other 3D metal telluride microstructures.

引用

页码：99 / 102

页数：4

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