Study on Mass Transfer during the Formation of PLLA 3-D Scaffolds by ScCO2 Induced Phase Separation

被引:0
|
作者
Ding, Zhaohong [1 ]
Liu, Zhijun [1 ]
Wei, Wei [1 ]
Li, Zhiyi [1 ]
机构
[1] Dalian Univ Technol, Sch Chem Engn, Inst Fluid & Power Engn, Dalian 116024, Peoples R China
来源
关键词
3-D scaffold; ScCO2 Induced Phase Separation; Mass Transfer; PLLA;
D O I
10.4028/www.scientific.net/AMR.550-553.849
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The two-way mass transfer behavior between solvent and non-solvent is a key factor effecting on the pore size and size distribution of 3-D scaffolds formed by ScCO2 induced phase separation process. The mathematical model of the mass transfer related to this process is presented on the basis of the model developed by Reuvers. By means of the composition paths calculated by this model in the ternary phase diagram, the pore size and size distribution of PLLA 3-D scaffolds are analyzed under different conditions (solution concentrations, CO2 pressures and temperatures).The calculated results are verified by experiment. The results show that the pore size of the PLLA 3-D scaffolds increases with the decrease of solution concentration and increase of the CO2 pressure and temperature.
引用
收藏
页码:849 / 854
页数:6
相关论文
共 50 条
  • [11] Tailorable Surface Morphology of 3D Scaffolds by Combining Additive Manufacturing with Thermally Induced Phase Separation
    Di Luca, Andrea
    de Wijn, Joost R.
    van Blitterswijk, Clemens A.
    Camarero-Espinosa, Sandra
    Moroni, Lorenzo
    MACROMOLECULAR RAPID COMMUNICATIONS, 2017, 38 (16)
  • [12] 3-D MODELING OF HEAT AND MASS TRANSFER PROCESS DURING THE COMBUSTION OF SOLID FUEL IN A SWIRL FURNACE
    Askarova, Aliya
    Bolegenova, Saltanat
    Maximov, Valeriy
    Bolegenova, Symbat
    Nugymanova, Aizhan
    Safarik, Pavel
    ACTA POLYTECHNICA, 2019, 59 (06) : 543 - 553
  • [13] 3-D MHD SIMULATION OF PLASMOID FORMATION DURING COALESCENCE OF 2 CURRENT LOOPS
    FUSHIKI, T
    SAKAI, JI
    SOLAR PHYSICS, 1995, 156 (02) : 265 - 280
  • [14] PVDF membrane formation by diffusion-induced phase separation-morphology prediction based on phase behavior and mass transfer modeling
    Cheng, LP
    Lin, DJ
    Shih, CH
    Dwan, AH
    Gryte, CC
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1999, 37 (16) : 2079 - 2092
  • [15] In vitro characterization of hierarchical 3D scaffolds produced by combining additive manufacturing and thermally induced phase separation
    Yousefi, Azizeh-Mitra
    Powers, Joseph
    Sampson, Kaylie
    Wood, Katherine
    Gadola, Carter
    Zhang, Jing
    James, Paul F.
    JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION, 2020, 32 (04) : 454 - 476
  • [16] Analysis of bijel formation dynamics during solvent transfer-induced phase separation using phase-field simulations
    Steenhoff, Jesse M.
    Haase, Martin F.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2025, 27 (10) : 5117 - 5130
  • [17] Membrane formation via phase separation induced by penetration of nonsolvent from vapor phase. I. Phase diagram and mass transfer process
    Matsuyama, H
    Teramoto, M
    Nakatani, R
    Maki, T
    JOURNAL OF APPLIED POLYMER SCIENCE, 1999, 74 (01) : 159 - 170
  • [18] Salami pattern formation during phase separation induced by polymerization of 2-chlorostyrene in the presence of polystyrene
    Tanabe, T
    Furukawa, H
    Okada, M
    POLYMER, 2003, 44 (17) : 4765 - 4768
  • [19] Modeling the effect of non-ideality, dynamic mass transfer and viscosity on SOA formation in a 3-D air quality model
    Kim, Youngseob
    Sartelet, Karine
    Couvidat, Florian
    ATMOSPHERIC CHEMISTRY AND PHYSICS, 2019, 19 (02) : 1241 - 1261
  • [20] I-Optimal Design of Hierarchical 3D Scaffolds Produced by Combining Additive Manufacturing and Thermally Induced Phase Separation
    Yousefi, Azizeh-Mitra
    Liu, Junyi
    Sheppard, Riley
    Koo, Songmi
    Silverstein, Joshua
    Zhang, Jing
    James, Paul F.
    ACS APPLIED BIO MATERIALS, 2019, 2 (02): : 685 - 696