Melt rheology and morphology of binary and ternary PS/HIPS blends for blown film extrusion applications

被引:11
|
作者
de Almeida, Karine Melro [1 ]
de Sousa, Ana Maria F. [2 ]
de Souza Junior, Fernando G. [1 ]
Bertolino, Luiz Carlos [3 ]
Rocha, Marisa C. G. [4 ]
Peres, Augusto C. C. [5 ]
Ossig, Andreia [6 ]
da Silva, Ana Lucia N. [1 ,7 ]
机构
[1] Univ Fed Rio de Janeiro, Inst Macromol Prof Eloisa Mano IMA UFRJ, Rio De Janeiro, RJ, Brazil
[2] Univ Estado Rio de Janeiro, Inst Quim IQ UERJ, Rio De Janeiro, RJ, Brazil
[3] Ctr Tecnol Mineral CETEM, Rio De Janeiro, RJ, Brazil
[4] Univ Estado Rio de Janeiro, Inst Politecn Rio de Janeiro IPRJ UERJ, Nova Friburgo, RJ, Brazil
[5] Ctr Pesquisa & Desenvolvimento Leopoldo Amer Migu, Rio De Janeiro, RJ, Brazil
[6] Univ Fed Rio Grande do Sul, Inst Quim IQ UFRGS, Porto Alegre, RS, Brazil
[7] Univ Fed Rio de Janeiro, Programa Engn Ambiental, Escola Politecn PEA UFRJ, Rio De Janeiro, RJ, Brazil
关键词
Polystyrene; Polymer blend; Rheology; Morphology; Blown film extrusion; RHEOTENS TEST; BUBBLE INSTABILITIES; DENSITY POLYETHYLENE; EXTENSIONAL RHEOLOGY; LDPE/LLDPE BLENDS; POLYMER MELTS; POLYSTYRENE; STRENGTH; STABILITY; DRAWABILITY;
D O I
10.1016/j.polymertesting.2017.10.016
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Rheology is an important tool for evaluating the potential application of a specific material in the production of blow molding films. In the present study, binary and ternary blends based on two different grades of polystyrene (PS) and high impact polystyrene (HIPS) were prepared by melt mixing in a twin screw extruder, using a simplex-centroid mixture design. Rheological analysis was performed based on elongational and dynamic rheology tests combined with scanning electron microscopy. Based on the rheology tests performed, the PS1/HIPS (50:50 wt.%) binary blend is a promising candidate for use in blow molding film applications.
引用
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页码:277 / 286
页数:10
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