MILD AND EFFICIENT CHEMOSELECTIVE TETRAHYDROPYRANYLATION OF ALCOHOLS USING BRONSTED ACIDIC IONIC LIQUID AS CATALYST UNDER SOLVENT-FREE CONDITIONS

被引:12
|
作者
Hajipour, Abdol R. [1 ,2 ]
Nasresfahani, Zahra [1 ]
机构
[1] Isfahan Univ Technol, Dept Chem, Pharmaceut Res Lab, Esfahan 84156, Iran
[2] Univ Wisconsin, Dept Pharmacol, Sch Med, Madison, WI 53706 USA
关键词
Alcohols; Bronsted acidic; ionic liquid; OTHP; protection; CARBONYL-COMPOUNDS; SOLID-PHASE; SELECTIVE TETRAHYDROPYRANYLATION; AROMATIC-COMPOUNDS; ALUMINUM-CHLORIDE; OXIDATION; REAGENT; SILICA; PHENOLS; IODINATION;
D O I
10.1080/00397911.2010.551286
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A straightforward and efficient method for preparation of morpholinium bisulfate ([mroH]HSO4) as a novel acidic ionic liquid is reported. The application of this efficient and inexpensive acidic ionic liquid catalyst for tetrahydropyranylation of alcohols under mild and solvent-free conditions at room was investigated.
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页码:1995 / 2006
页数:12
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