Anion-controlled assembly of low-dimensional silver(I) complexes of 2-(3-pyridyl)benzimidazole (PyBIm)

被引：27

作者：

Su, CY

Yang, XP

Liao, S

Mak, TCW

Kang, BS ^{[1
]}

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China

[2] Chinese Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 09期

基金：

中国国家自然科学基金;

关键词：

silver complexes; 2-(3-pyridyl)benzimidazole; Low dimensional structures; weak interactions; crystal structures;

D O I：

10.1016/S1387-7003(99)00100-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The silver(I) complexes of 2-(3-pyridyl)benzimidazole (PyBLm) [Ag-2(PyBIm)(2)](A)(2) (A=ClO4- (1) and CF3SO3- (2)) were prepared and the structures characterized by X-ray crystallography. The networks of the dinuclear complexes are extended via weak interactions between the cations and anions and controlled by the latter. Each cation in both complexes has the Ag atoms bridged by two PyBIm ligands via the N-py and N-Blm donor atoms in quasi-linear geometry. The 1D-chain (1) and 2D-sheet (2) structures were further constructed via intermolecular Ag ... O, Ag ... F and NH ... O interactions. (C) 1999 Elsevier Science S.A, All rights reserved.

引用

页码：383 / 385

页数：3

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