Cadmium(II) complex with (1'H-[2,2']biimidazoly-1-YL)-acetic acid: Synthesis, crystal structure, and luminescence

被引：1

作者：

Wang, J. ^{[1
]}

Tao, J. -Q. ^{[1
]}

Xu, X. -J. ^{[1
]}

Tan, C. -Y. ^{[1
]}

机构：

[1] Yancheng Teachers Coll, Dept Chem, Yancheng, Jiangsu, Peoples R China

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 54卷 / 03期

关键词：

Cd(II) complex; crystal structure; hydrogen bonding; C-O center dot center dot center dot pi interaction; photoluminescence; LIGAND;

D O I：

10.1134/S0022476613030128

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new cadmium(II) complex with (1'H-[2,2']Biimidazoly-1-yl)-acetic acid (HBDAC) [Cd(BDAC)(2)(H2O)(2)]center dot H2O is synthesized and structurally characterized, which crystallizes in the monoclinic system, space group P2(1)/c, a = 8.465(3) , b = 14.164(5) , c = 11.294(3) , alpha = 90A degrees, beta = 127.405(17)A degrees, gamma = 90A degrees, Z = 2. The [Cd(BDAC)(2)(H2O)(2)]center dot H2O units are further bridged by O-HaEuro broken vertical bar O, N-HaEuro broken vertical bar O, C-HaEuro broken vertical bar O hydrogen bonds, pi-pi stacking and C-OaEuro broken vertical bar pi interactions, generating a three-dimensional supramolecular structure. In addition, luminescence measurements reveal that complex 1 exhibits strong fluorescent emission in the solid state at room temperature.

引用

页码：555 / 559

页数：5

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