Catalytic methoxycarbonylation of 1,6-hexamethylenediamine with methyl carbamate to dimethylhexane-1,6-dicarbamate

被引：2
|
作者：
Han, Bing [1 ]
Zhao, Wenbo [1 ]
Qin, Xianye [1 ]
Li, Yanhong [1 ]
Wei, Wei
机构：
[1] Kunming Univ Sci & Technol, Fac Chem Engn, Kunming 650500, Peoples R China
来源：
ADVANCES IN CHEMICAL, MATERIAL AND METALLURGICAL ENGINEERING, PTS 1-5 | 2013年 / 634-638卷
关键词：
1,6-hexamethylenediamine; methyl carbamate; dimethylhexane-1,6-dicarbamate; lead dioxide; metal oxide; DIMETHYL CARBONATE; ALKYL CARBAMATE;
D O I：
10.4028/www.scientific.net/AMR.634-638.490
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A series of metal oxides were employed as catalysts for the synthesis of dimethylhexane -1,6-dicarbamate(HDC) from 1,6-hexamethylenediamine(HDA) and methyl carbonate(MC). Lead dioxide showed excellent catalytic activity, 100% HDA conversion and 93% HDC yield could be achieved at 463K for 6h. The effects of reaction temperature, reaction time and catalyst amount on the yield of HDC were investigated in details.
引用
收藏
页码：490 / 493
页数：4
相关论文
共 50 条
  • [41] Passivating Charged Defects with 1,6-Hexamethylenediamine To Realize Efficient and Stable Tin-Based Perovskite Solar Cells
    Ma, Ben
    Chen, Junwen
    Wang, Minghao
    Xu, Xin
    Qian, Jie
    Lu, Yao
    Zhang, Wenzhu
    Xia, Pengfei
    Qin, Minchao
    Zhu, Wenjing
    Zhang, Liuquan
    Chen, Shufen
    Lu, Xinhui
    Huang, Wei
    JOURNAL OF PHYSICAL CHEMISTRY C, 2020, 124 (30): : 16289 - 16299
  • [42] SYNTHESIS OF BINUCLEAR PT(II) COMPLEXES WITH N,N,N',N'-TETRAKIS(2-AMINOETHYL)-1,6-HEXAMETHYLENEDIAMINE
    VLASOV, VV
    KAZAKOV, SA
    MISOVETS, VG
    DOKLADY AKADEMII NAUK SSSR, 1982, 266 (04): : 866 - 870
  • [43] Synthesis of dimethacryloxy ethyl-1,1,6,6-tetrahydro-perfluorohexamethylene-1,6-dicarbamate as dental base monomers and the mechanical properties of the copolymers of the monomer and methyl methacrylate
    Kurata, Shigeaki
    Yamazaki, Noboru
    DENTAL MATERIALS JOURNAL, 2011, 30 (01) : 103 - 108
  • [44] Novel Bioproduction of 1,6-Hexamethylenediamine from <sc>l</sc>-Lysine Based on an Artificial One-Carbon Elongation Cycle
    Xiao, Kaixing
    Wang, Dan
    Liu, Xuemei
    Kang, Yaqi
    Luo, Ruoshi
    Hu, Lin
    Peng, Zhiyao
    ACS OMEGA, 2024, 9 (39): : 40970 - 40979
  • [45] One-Pot Synthesis of Dialkyl Hexane-1,6-Dicarbamate from 1,6-Hexanediamine, Urea, and Alcohol over Zinc-Incorporated Berlinite (ZnAlPO4) Catalyst
    Sun, Da-Lei
    Mai, Ji-Jin
    Deng, Jian-Ru
    Idem, Raphael
    Liang, Zhi-Wu
    CATALYSTS, 2016, 6 (02):
  • [46] One-Pot Biocatalytic Transformation of Adipic Acid to 6-Aminocaproic Acid and 1,6-Hexamethylenediamine Using Carboxylic Acid Reductases and Transaminases
    Fedorchuk, Tatiana P.
    Khusnutdinova, Anna N.
    Evdokimova, Elena
    Flick, Robert
    Di Leo, Rosa
    Stogios, Peter
    Savchenko, Alexei
    Yakunin, Alexander F.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (02) : 1038 - 1048
  • [47] Metabolic engineering combined with site-directed saturated mutations of α-keto acid decarboxylase for efficient production of 6-aminocaproic acid and 1,6-hexamethylenediamine
    Wang, Tiantian
    Ye, Pan
    Xu, Xue
    Lu, Mengqing
    Zhang, Xinyu
    Li, Naiqiang
    BIOTECHNOLOGY AND BIOENGINEERING, 2024, 121 (10) : 3329 - 3337
  • [48] Efficient synthesis of 1,6-hexamethylene diurethane through coupling transesterification and methoxycarbonylation with methyl phenyl carbonate as intermediate
    Yang, Yong
    Tang, Jihai
    Chen, Xian
    Fei, Zhaoyang
    Cui, Mifen
    Qiao, Xu
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2015, 23 (07) : 1147 - 1152
  • [49] CHROMATOGRAPHIC DETERMINATION OF AMINES IN BIOLOGICAL-FLUIDS WITH SPECIAL REFERENCE TO THE BIOLOGICAL MONITORING OF ISOCYANATES AND AMINES .1. DETERMINATION OF 1,6-HEXAMETHYLENEDIAMINE USING GLASS-CAPILLARY GAS-CHROMATOGRAPHY AND THERMIONIC SPECIFIC DETECTION
    SKARPING, G
    DALENE, M
    BRORSON, T
    SANDSTROM, JF
    SANGO, C
    TILJANDER, A
    JOURNAL OF CHROMATOGRAPHY, 1989, 479 (01): : 125 - 133
  • [50] CHROMATOGRAPHIC DETERMINATION OF AMINES IN BIOLOGICAL-FLUIDS WITH SPECIAL REFERENCE TO THE BIOLOGICAL MONITORING OF ISOCYANATES AND AMINES .4. DETERMINATION OF 1,6-HEXAMETHYLENEDIAMINE IN HUMAN URINE USING CAPILLARY GAS-CHROMATOGRAPHY AND SELECTIVE ION MONITORING
    DALENE, M
    SKARPING, G
    BRORSON, T
    JOURNAL OF CHROMATOGRAPHY, 1990, 516 (02): : 405 - 413
12345