Synthesis of chalcogeno[3-(pyrid-2-yl)-1-azaallyl]germanium complexes

被引：27
|
作者：
Leung, WP [1 ]
Chong, KH [1 ]
Wu, YS [1 ]
So, CW [1 ]
Chan, HS [1 ]
Mak, TCW [1 ]
机构：
[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 04期
关键词：
chalcogens; germanium; N ligands;
D O I：
10.1002/ejic.200500717
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of [Ge{C(C5H4N-2)C(Ph)N(SiMe3)(2)}{N(SiMe3)C(Ph)C(SiMe3)(C5H4N-2)}] (1) and [Ge{N(SiMe3)C(Ph)C(SiMe3)(C5H4N-2))Cl] (2) with stoichiometric amounts of elemental chalcogens in toluene affords [Ge(E){C(C5H4N-2)C(Ph)N(SiMe3)(2))(N(SiMe3)C(Ph)C(SiMe3)(C5H4N-2)}] [E = S (3), Se (4)] and [Ge(E)IN(SiMe3)C(Ph)C(SiMe3)(C5H4N-2)}Cl] [E = S (5), Se (6)], respectively. Compounds 3-6 were characterized by X-ray analysis. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).
引用
收藏
页码：808 / 812
页数：5
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