In Situ Quaternized Gel Electrolyte For Quasi-Solid-State Dye-Sensitized Solar Cell

被引：0
|
作者：
Dai, Yuhua [1 ]
Sun, Xiaolei [1 ]
Wang, Jinglian [1 ]
Yang, Mingshan [1 ]
机构：
[1] Beijing Inst Petrochem Technol, Dept Mat Sci & Engn, Beijing 102617, Peoples R China
来源：
ADVANCED MATERIALS, PTS 1-3 | 2012年 / 415-417卷
关键词：
In situ quaterisation reaction; polymer gel electrolyte; dye-sensitized solar cells;
D O I：
10.4028/www.scientific.net/AMR.415-417.1586
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A series of copolymers P(VP-HEMA) composed of hydroxyl ethyl methacrylate (HEMA) and 4-vinyl pyridine (VP) were prepared by a solution copolymerization technique. Based on the copolymer P(VP-HEMA) prepared by the content of VP 50%, the amount of AIBN 3% and the optimized liquid electrolyte, a polymer solution electrolyte with concentration of 9.0% was formed. By addition of 1,4-dibromobutane into the solution, the copolymer gel electrolyte with higher conductivity 6.14mS/cm was prepared. Gelation is caused by the quaterisation between the group of pyridine in P(HEMA-VP) and 1,4-dibromobutane. Based on the copolymer gel electrolyte, a dye-sensitized solar cell was fabricated with short-circuit current of 13.62mA/cm(2),open circuit voltage of 0.72V, fill factor of 0.5465 and an overall conversion efficiency of 5.24% under irradiation 100mW/cm(2) (AM1.5).
引用
收藏
页码：1586 / 1589
页数：4
相关论文
共 50 条
  • [21] Polymer-metal complex as gel electrolyte for quasi-solid-state dye-sensitized solar cells
    Xiang, Wanchun
    Fang, Yanyan
    Lin, Yuan
    Fang, Shibi
    ELECTROCHIMICA ACTA, 2011, 56 (03) : 1605 - 1610
  • [22] Influence of Polymer Concentration on Polysaccharide Electrolyte for Quasi-solid-state Dye-sensitized Solar Cell
    Yang, Ying
    Guo, Xue-Yi
    Zhao, Xing-Zhong
    ENERGY, ENVIRONMENT AND BIOLOGICAL MATERIALS, 2011, 685 : 76 - +
  • [23] A quasi-solid-state dye-sensitized solar cell based on porous polymer electrolyte membrane
    Zhang, Xiao
    Wang, Cong-Xiao
    Li, Fu-You
    Xia, Yong-Yao
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2008, 194 (01) : 31 - 36
  • [24] Gelation of a liquid electrolyte with aniline for use in a quasi-solid-state dye-sensitized solar cell
    Lan Zhang
    Wu JiHuai
    Un JianMing
    Huang MiaoLiang
    SCIENCE CHINA-CHEMISTRY, 2012, 55 (02) : 242 - 246
  • [25] Erratum: A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer gel electrolyte
    Peng Wang
    Shaik M. Zakeeruddin
    Jacques E. Moser
    Mohammad K. Nazeeruddin
    Takashi Sekiguchi
    Michael Grätzel
    Nature Materials, 2003, 2 : 498 - 498
  • [26] Application of Thermosetting Organic Solvent Free Polymer Gel Electrolyte in Quasi-Solid-State Dye-Sensitized Solar Cell
    Lan, Zhang
    Wu, Jihuai
    Lin, Jianming
    Huang, Miaoliang
    JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 116 (03) : 1329 - 1333
  • [27] Enhanced performance of a quasi-solid-state dye-sensitized solar cell with aluminum nitride in its gel polymer electrolyte
    Huang, Kuan-Chieh
    Chen, Po-Yen
    Vittal, R.
    Ho, Kuo-Chuan
    SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2011, 95 (08) : 1990 - 1995
  • [28] A POLYMER GEL ELECTROLYTE BASED ON P(MMA-NVP) FOR QUASI-SOLID-STATE DYE-SENSITIZED SOLAR CELL
    Dan, Yuhua
    Sun, Xiaolei
    Shi, Qiufei
    Yang, Mingshan
    RENEWABLE AND SUSTAINABLE ENERGY, PTS 1-7, 2012, 347-353 : 124 - 127
  • [29] Quasi-solid-state dye-sensitized solar cells with siloxane poly(ethylene glycol) hybrid gel electrolyte
    Joseph, James
    Son, Kyung Mo
    Vittal, R.
    Lee, Whasup
    Kim, Kang-Jin
    SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2006, 21 (05) : 697 - 701
  • [30] A quasi-solid-state dye-sensitized solar cell based on a sol-gel nanocomposite electrolyte containing ionic liquid
    Stathatos, E
    Lianos, P
    Zakeeruddin, SM
    Liska, P
    Grätzel, M
    CHEMISTRY OF MATERIALS, 2003, 15 (09) : 1825 - 1829
12345