Fluorescent azadipyrrinato zinc(II) complex: hybridisation with a dipyrrinato ligand

被引:27
|
作者
Sakamoto, Ryota [1 ]
Kusaka, Shinpei [1 ]
Kitagawa, Yasutaka [2 ]
Kishida, Masa-aki [1 ]
Hayashi, Mikihiro [1 ]
Takara, Yusuke [1 ]
Tsuchiya, Mizuho [1 ]
Kakinuma, Junko [1 ]
Takeda, Takuma [1 ]
Hirata, Keisuke [1 ]
Ogino, Tomoya [1 ]
Kawahara, Keisuke [1 ]
Yagi, Toshiki [1 ]
Ikehira, Shu [1 ]
Nakamura, Tomoya [1 ]
Isomura, Mayuko [1 ]
Toyama, Mikoto [1 ]
Ichikawa, Saki [1 ]
Okumura, Mitsutaka [2 ]
Nishihara, Hiroshi [1 ]
机构
[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan
[2] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 0560043, Japan
关键词
SOLAR-CELLS; AZADIPYRROMETHENE COMPLEXES; SPECTROSCOPIC PROPERTIES; BODIPY DYES; DERIVATIVES; SENSITIZERS; ABSORPTION; TISSUE; BORON;
D O I
10.1039/c2dt32039h
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
We synthesised heteroleptic azadipyrrinato-dipyrrinato hybrid zinc(II) complex 1-Zn-2, by means of the stepwise coordination method. Homoleptic bis(azadipyrrinato)zinc(II) complex 1-Zn-1 was non-fluorescent, whereas 1-Zn-2 exhibited detectable fluorescence from azadipyrrinato ligand 1.
引用
收藏
页码:14035 / 14037
页数:3
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