NMR and EPR Spectroscopy Applied to Homogeneous Catalysis

被引：1
|
作者：
Talzi, E. P. [1 ,2 ]
Brylyakov, K. P. [1 ,2 ]
Lyakin, O. Yu. [1 ,2 ]
Zima, A. M. [1 ,2 ]
Soshnikov, I. E. [1 ,2 ]
机构：
[1] Novosibirsk State Univ, Novosibirsk 630090, Russia
[2] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia
来源：
KINETICS AND CATALYSIS | 2015年 / 56卷 / 04期
基金：
俄罗斯科学基金会;
关键词：
NMR spectroscopy; EPR spectroscopy; homogeneous catalysis; active sites of catalysts; olefin epoxidation; olefin polymerization; NONHEME IRON; ETHYLENE POLYMERIZATION; ZIEGLER-NATTA; H-2; NMR; C-H; H2O2; ACTIVATION; EPOXIDATION; FE; HYDROXYLATION;
D O I：
10.1134/S0023158415040175
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The article deals with applying NMR and EPR spectroscopy to the study of the active sites of catalysts in two important classes of reactions: enantioselective olefin epoxidation with hydrogen peroxide catalyzed by iron aminopyridine complexes and olefin polymerization in the presence of titanium and vanadium post-metallocene catalysts.
引用
收藏
页码：484 / 492
页数：9
相关论文
共 50 条
  • [41] Enzyme dynamics during catalysis measured by NMR spectroscopy
    Kern, D
    Eisenmesser, EZ
    Wolf-Watz, M
    NUCLEAR MAGNETIC RESONANCE OF BIOLOGICAL MACROMOLECULES, PART C, 2005, 394 : 507 - 524
  • [42] X-RAY PHOTOELECTRON-SPECTROSCOPY AND HOMOGENEOUS CATALYSIS
    LARSSON, R
    FOLKESSON, B
    LYKVIST, R
    CHEMICA SCRIPTA, 1979, 13 (05): : 178 - 185
  • [43] APPLICATION OF ESR AND NMR IN STUDYING PARAMAGNETIC-COMPLEXES IN HOMOGENEOUS CATALYSIS
    ZAMARAEV, KI
    KINETICS AND CATALYSIS, 1980, 21 (02) : 223 - 235
  • [44] NMR AT ELEVATED GAS-PRESSURES AND ITS APPLICATION TO HOMOGENEOUS CATALYSIS
    ELSEVIER, CJ
    JOURNAL OF MOLECULAR CATALYSIS, 1994, 92 (03): : 285 - 297
  • [45] High pressure NMR flow cell for the in situ study of homogeneous catalysis
    Iggo, JA
    Shirley, D
    Tong, NC
    NEW JOURNAL OF CHEMISTRY, 1998, 22 (10) : 1043 - 1045
  • [46] A primer in pulse EPR-based hyperfine spectroscopy for NMR spectroscopists
    Wili, Nino
    JOURNAL OF MAGNETIC RESONANCE OPEN, 2023, 16-17
  • [47] CHIRAL RECOGNITION BY H-1-NMR, EPR, AND ENDOR SPECTROSCOPY
    STEGMANN, HB
    MAURER, M
    HOFLER, U
    SCHEFFLER, K
    HEWGILL, F
    CHIRALITY, 1993, 5 (04) : 282 - 287
  • [48] VERY HIGH-FREQUENCY EPR SPECTROSCOPY AND NMR IMAGING OF COAL
    CLARKSON, RB
    MOTSEGOOD, K
    WANG, W
    WEBB, AG
    BELFORD, RL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 202 : 74 - FUEL
  • [49] Partitioning of nitroxides in dispersed systems investigated by ultrafiltration, EPR and NMR spectroscopy
    Krudopp, Heimke
    Soennichsen, Frank D.
    Steffen-Heins, Anja
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2015, 452 : 15 - 23
  • [50] Metal-dependent folding and catalysis in ribozymes: Applications of SDSL and EPR spectroscopy
    DeRose, Victoria J.
    Kim, Nak-Kyoon
    Murali, Ayaluru
    Bowman, Michael K.
    Green, Kathryn
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 232 : 791 - 791
12345