1D and 2D NMR study of ionic conductivity in CsDSO4

被引：11
|
作者：
Lahajnar, G
Blinc, R
Dolinsek, J
Arcon, D
Slak, J
机构：
来源：
SOLID STATE IONICS | 1997年 / 97卷 / 1-4期
关键词：
protonic conductor; 2D exchange NMR; deuteron motion;
D O I：
10.1016/S0167-2738(97)00084-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Cs-133 and deuteron NMR measurements of the superionic transition in CsDSO4 showed that the mechanism of protonic conductivity involves thermally-activated hopping of deuterons over well-defined lattice sites. The present 2D NMR study of O-D...O deuteron interbond motion provided evidence that slow deuteron exchange between two differently oriented hydro en bonds in the unit cell of CsDSO4 already takes place at room temperature, thus indicating precursor effects of the superionic transition far below the transition temperature T-0 = 412 K.
引用
收藏
页码：141 / 144
页数：4
相关论文
共 50 条
  • [31] 1D analogues of homonuclear 2D NMR by DANTE-selective pulses
    Flood, TA
    CONCEPTS IN MAGNETIC RESONANCE, 1996, 8 (02): : 119 - 138
  • [32] Mixed micelles of polyethylene glycol (23) lauryl ether with ionic surfactants studied by proton 1D and 2D NMR
    Gao, HC
    Zhao, S
    Mao, SZ
    Yuan, HZ
    Yu, JY
    Shen, LF
    Du, YR
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 249 (01) : 200 - 208
  • [33] 1D metals for 2D electronics
    Jolie, Wouter
    Michely, Thomas
    NATURE NANOTECHNOLOGY, 2024, 19 (07) : 883 - 884
  • [34] Classification of 1D and 2D Orbifolds
    Nilse, Lars
    SUSY06: The 14th International Conference on Supersymmetry and the Unification of Fundamental Interactions, 2007, 903 : 411 - 414
  • [35] Optimisation of 1D and 2D in vivo 1H NMR to study tropane alkaloid metabolism in Pseudomonas
    Bartholomeusz, Trixie Ann
    Molinie, Roland
    Mesnard, Francois
    Robins, Richard J.
    Roscher, Albrecht
    COMPTES RENDUS CHIMIE, 2008, 11 (4-5) : 457 - 464
  • [36] A Comprehensive Study of 1D and 2D Image Interpolation Techniques
    Earshia, V. Diana
    Sumathi, M.
    ICCCE 2018, 2019, 500 : 383 - 391
  • [37] Study of 1D and 2D Carbon Nanomaterial in Alginate Films
    Salesa, Beatriz
    Llorens-Gamez, Mar
    Serrano-Aroca, Angel
    NANOMATERIALS, 2020, 10 (02)
  • [38] A study of topological effects in 1D and 2D mechanical lattices
    Chen, H.
    Nassar, H.
    Huang, G. L.
    JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS, 2018, 117 : 22 - 36
  • [39] 1D and 2D network of ReO-4 bonded azoimidazoles
    Ray, U
    Chand, B
    Dasmahapatra, AK
    Mostafa, G
    Lu, TH
    Sinha, C
    INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (06) : 634 - 638
  • [40] Intra- and inter-molecular interactions in choline-based ionic liquids studied by 1D and 2D NMR
    Veroutis, Emmanouil
    Merz, Steffen
    Eichel, Rudiger A.
    Granwehr, Josef
    JOURNAL OF MOLECULAR LIQUIDS, 2021, 322
12345