Isomerization of light naphtha over sulfur tolerant Pd/SO42-/ZrO2-Al2O3 catalyst

被引:3
|
作者
Watanabe, K
Kawakami, T
Baba, K
Oshio, N
Kimura, T
机构
[1] Cosmo Oil Co Ltd, Ctr Res & Dev, Satte, Saitama 3040193, Japan
[2] Cosm Oil Co Ltd, Int Cooperat Ctr, Minato Ku, Tokyo 1808564, Japan
关键词
sulfated zirconia catalyst; palladium catalyst; light naphtha; skeletal isomerization; sulfur tolerance;
D O I
10.1627/jpi.47.143
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Isomerization of organic sulfur containing light naphtha was studied over metal sulfated zirconium catalyst. Even in the presence of sulfur compounds, Pd/SO42-/ZrO2-Al2O3 catalyst indicated the high isomerization activity without catalyst deactivation. We supposed that isomerization activity was kept by continuous regeneration of the dehydrogenation active site through the desulfurization of sulfur compounds deposited on catalyst by Pd.
引用
收藏
页码:143 / 144
页数:2
相关论文
共 50 条
  • [21] Stability of PdO-Re2O7/SO42-/ZrO2-Al2O3 Catalyst for Direct Synthesis of Propylene From Ethylene
    Sayfulina, L. F.
    Buluchevskiy, E. A.
    Lavrenov, A., V
    Arbuzov, A. B.
    Karpova, T. R.
    21ST CENTURY: CHEMISTRY TO LIFE, 2019, 2143
  • [22] Catalytic conversion of xylose to furfural over the solid acid SO42-/ZrO2-Al2O3/SBA-15 catalysts
    Shi, Xuejun
    Wu, Yulong
    Li, Panpan
    Yi, Huaifeng
    Yang, Mingde
    Wang, Gehua
    CARBOHYDRATE RESEARCH, 2011, 346 (04) : 480 - 487
  • [23] Comparison of structure and properties of catalyst SO42-/ZrO2-SiO2 with catalyst SO42-/ZrO2
    Liao, Shijun
    Hu, Jihua
    Liang, Luyi
    Yu, Wenwei
    Zhu, Jifang
    Wang, Lefu
    Huanan Ligong Daxue Xuebao/Journal of South China University of Technology (Natural Science), 1998, 26 (10): : 47 - 53
  • [24] High-activity catalyst of SO42-/ZrO2 supported on γ-Al2O3 for n-butane isomerization
    Lei, T
    Xu, JS
    Hua, WM
    Tang, Y
    Gao, Z
    CATALYSIS LETTERS, 1999, 61 (3-4) : 213 - 218
  • [25] Kinetics Model of the n-Hexane Isomerization Catalyzed by Pt-SO42-/ZrO2-Al2O3
    Zhang, Kongyuan
    Cui, Mengda
    Huang, Renqiang
    Ma, Liang
    Liu, Chenguang
    Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section), 2023, 39 (02): : 300 - 309
  • [26] Study of n-hexane isomerization on mixed Al2O3-ZrO2/SO42- catalysts
    Guevara-Franco, ML
    Robles-Andrade, S
    García-Alamilla, R
    Sandoval-Robles, G
    Domínguez-Esquivel, JM
    CATALYSIS TODAY, 2001, 65 (2-4) : 137 - 141
  • [27] Study on preparation of SO42-/ZrO2-Al2O3 solid superacid by improving preparation condition and adding lanthanum
    Chen, TY
    Gu, XP
    Wan, YB
    CHINESE JOURNAL OF CHEMICAL PHYSICS, 2002, 15 (01) : 75 - 78
  • [28] 固体酸SO42-/ZrO2-Al2O3催化合成乙腈的研究
    侯雪梅
    闫丽
    张鑫
    李艳伟
    李传碧
    吉林师范大学学报(自然科学版), 2009, 30 (02) : 108 - 109
  • [29] SO42-/ZrO2-Al2O3催化合成糠酸酯类香料的研究
    杨辉荣
    张静
    张红
    廖松
    精细化工, 1999, (02) : 19 - 22
  • [30] Isomerization reactions with sulfur-containing pentane over metal/SO42-/ZrO2 catalysts
    Watanabe, K
    Oshio, N
    Kawakami, T
    Kimura, T
    APPLIED CATALYSIS A-GENERAL, 2004, 272 (1-2) : 281 - 287