Effect of the Phase Composition of Molybdenum Boride on its Catalytic Properties in the Epoxidation of 1-Octene by tert-Butyl Hydroperoxide

被引：1

作者：

Nykypanchuk, M. V. ^{[1
]}

Komarenskaya, Z. M. ^{[1
]}

Zhukrovskaya, M. O. ^{[2
]}

机构：

[1] Natl Univ, Lviv Polytech, S Bandery St 12, UA-79013 Lvov, Ukraine

[2] Lviv Inst Nursing & Lab Med, Doroshenka St 70, UA-79013 Lvov, Ukraine

来源：

THEORETICAL AND EXPERIMENTAL CHEMISTRY | 2019年 / 54卷 / 06期

关键词：

molybdenum boride; catalyst; activation; epoxidation; octene-1; tert-butyl hydroperoxide;

D O I：

10.1007/s11237-019-09588-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It was shown that the epoxidation of 1-octene by tert-butyl hydroperoxide in the presence of Mo2B is accompanied by the formation of an amorphous oxygen-containing phase on its surface. It was established that this is the phase that catalyzes the reaction and determines its speed and selectivity.

引用

页码：407 / 413

页数：7

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