Analytical characterization, occurrence, transformation, and removal of the emerging disinfection byproducts halobenzoquinones in water

被引:69
|
作者
Wang, Wei [1 ]
Moe, Birget [1 ]
Li, Jinhua [1 ]
Qian, Yichao [1 ]
Zheng, Qi [2 ,3 ]
Li, Xing-Fang [1 ]
机构
[1] Univ Alberta, Div Analyt & Environm Toxicol, Dept Lab Med & Pathol, Fac Med & Dent, Edmonton, AB T6G 2G3, Canada
[2] Jianghan Univ, Key Lab Optoelect Chem Mat & Devices, Minist Educ, Wuhan 430056, Peoples R China
[3] Jianghan Univ, Inst Environm & Hlth, Wuhan 430056, Peoples R China
基金
加拿大自然科学与工程研究理事会;
关键词
Disinfection byproducts; Halobenzoquinones; Occurrence; Removal; Liquid chromatography-tandem mass spectrometry; Solid phase extraction; Water analysis; SOLID-PHASE EXTRACTION; BASIDIOMYCETE PHANEROCHAETE-CHRYSOSPORIUM; CHROMATOGRAPHY-MASS-SPECTROMETRY; SYNTHETIC PHENOLIC ANTIOXIDANTS; METAL-INDEPENDENT PRODUCTION; DRINKING-WATER; ELECTROSPRAY-IONIZATION; HPLC METHOD; HYDROGEN-PEROXIDE; AQUEOUS-SOLUTION;
D O I
10.1016/j.trac.2016.03.004
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Water disinfection can create an unintended chemical risk from the formation of disinfection byproducts (DBPs). Epidemiological studies have shown a potential association of water disinfection with an increased risk of bladder cancer. The DBPs responsible for the observed adverse health effects remain unclear. Identification of DBPs of health relevance presents a great analytical challenge. Halobenzoquinones (HBQs) are a unique class of emerging DBPs of potential toxicological relevance. This review presents the analytical characterization, occurrence, formation, transformation, and removal of HBQDBPs in drinking water. Specifically, we will discuss the challenges of HBQ analytical method development and the resulting solid phase extraction and high performance liquid chromatography-tandem mass spectrometry techniques that achieve the determination of HBQs at ng/L, levels in water. Other techniques for HBQ analysis, including ultraviolet-visible spectroscopy, electron spin resonance, and gas chromatography-mass spectrometry, will be briefly discussed. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:97 / 110
页数:14
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