Spontaneous Resolution of a Mixed-Ligand Nickel(II) Coordination Polymer with Achiral Precursors

被引：71
|
作者：
Bisht, Kamal Kumar
Suresh, Eringathodi [1 ]
机构：
[1] CSIR, Analyt Discipline, Cent Salt & Marine Chem Res Inst, Bhavnagar 364002, Gujarat, India
来源：
INORGANIC CHEMISTRY | 2012年 / 51卷 / 18期
关键词：
METAL-ORGANIC FRAMEWORK; INDUCTION; NETWORKS; ACID;
D O I：
10.1021/ic301636z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Metal-center-driven spontaneous resolution of a chiral coordination polymer, [Ni(SDB)(BIX)](n) (1), from achiral precursors has been probed by single-crystal X-ray diffraction and circular dichroism spectroscopy. Enantiomorphs 1P and 1M showed a parallel interpenetrated 2D -> 3D chiral framework with (8(2).10) topology. Switching of the metal center under the same reaction parameters resulted in isostructural achiral and noninterpenetrating (4,4) grid-type sql networks [M(SDB)(BIX)](n), where M = Co-II, Zn-II, and Cd-II for 2-4, respectively.
引用
收藏
页码：9577 / 9579
页数：3
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