Conversion of primary amines into secondary amines on a metal-organic framework using a tandem post-synthetic modification

被引：16
|
作者：
Burrows, Andrew D. [1 ]
Keenan, Luke L. [1 ]
机构：
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
来源：
CRYSTENGCOMM | 2012年 / 14卷 / 12期
关键词：
POSTSYNTHETIC MODIFICATION; COVALENT MODIFICATION; FUNCTIONALIZATION; REACTIVITY; TOPOLOGY; MOFS;
D O I：
10.1039/c2ce25131k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The amine-functionalised metal-organic framework (MOF) [Zn4O(bdc-NH2)(3)] (IRMOF-3, bdc-NH2 = 2-amino-1,4-benzenedicarboxylate) has been post-synthetically modified in a tandem condensation-reduction process into secondary amine-containing MOFs. The degree of modification is enhanced by introduction of methanol, which helps to remove boron-containing side-products from the pores.
引用
收藏
页码：4112 / 4114
页数：3
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