Synthesis of n-type semiconducting polymer consisting of benzodipyrrolidone and thieno-[3,4-c]-pyrrole-4,6-dione via C-H direct arylation

被引：11
|
作者：
Wang, Zhi An [1 ]
Kuwabara, Junpei [1 ]
Ichige, Akito [1 ]
Yasuda, Takeshi [2 ]
Kanbara, Takaki [1 ]
机构：
[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba Res Ctr Interdisciplinary Mat Sci TIMS, 1-1-1 Tennodai, Tsukuba, Ibaraki 3058573, Japan
[2] Natl Inst Mat Sci, Funct Mat Res Ctr, 1-2-1 Sengen, Tsukuba, Ibaraki 3050047, Japan
来源：
SYNTHETIC METALS | 2016年 / 222卷
关键词：
Conjugated polymers; Benzodipyrrolidone; Polycondensation; Direct arylation; N-type semiconducting material; PI-CONJUGATED POLYMERS; POWER CONVERSION EFFICIENCY; CATALYZED DIRECT ARYLATION; DONOR-ACCEPTOR POLYMERS; NAPHTHALENE DIIMIDE; SOLAR-CELLS; ALTERNATING COPOLYMERS; ORGANIC PHOTOVOLTAICS; HIGH-MOBILITY; POLYCONDENSATION;
D O I：
10.1016/j.synthmet.2016.10.014
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Direct arylation polycondensation of 3,7-bis(4-bromophenyl)-1,5-bis(2-octyldodecyl)benzo[1,2-b:4,5-b'] dipyrrole-2,6(1H,5H)-dione with 5-(2-ethylhexyl)-thieno-[3,4-c]-pyrrole-4,6-dione gave the corresponding benzodipyrrolidone-based conjugated polymer with a molecular weight of 147,000 in 92% yield. The optical and thermal properties of the polymer were evaluated. The polymer showed n -type semiconducting behavior in organic field-effect transistors with an electron mobility of 1.3 +/- 0.2 x 10(-3 cm2) V-1 s(-1). (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：383 / 387
页数：5
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